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引用次数: 0
摘要
封面展示了在锂介导的氮还原反应过程中,利用可再生电力从氮气和质子源(乙醇)电合成氨的过程。氮的活化和还原发生在阴极上形成的固体电解质界面层上,该界面层包括无机含锂层和来自电解质的有机分子。这项研究发现了氮化耦合还原机制和氮循环还原机制。更多信息请参阅 C. Zhou 和 Q. Zhao 的研究文章(DOI: 10.1002/cphc.202401097)。
Front Cover: Revealing Mechanisms of Lithium-Mediated Nitrogen Reduction Reaction from First-Principles Simulations (ChemPhysChem 7/2025)
The Front Cover shows the electrosynthesis of ammonia from nitrogen gas and a proton source (ethanol) powered by renewable electricity in the process of the lithium-mediated nitrogen reduction reaction. Nitrogen activation and reduction happens on a solid electrolyte interface layer formed on a cathode, which has an inorganic lithium-containing layer and organic molecules derived from electrolytes. This work uncovers a nitridation-coupled reduction mechanism and a nitrogen cycling reduction mechanism. More information can be found in the Research Article by C. Zhou and Q. Zhao (DOI: 10.1002/cphc.202401097).
期刊介绍:
ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.