3-叠氮-1,5-二烯的光催化区域选择性烷氧羰基化/环化：获得含酯吡咯啉-2-酮

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-03-13 DOI:10.1021/acs.orglett.5c0069410.1021/acs.orglett.5c00694

Yuping Xiong, Zhipeng Zong, Wenlin Xie*, Jian-Qiang Chen* and Jie Wu*,

引用次数: 0

摘要

报道了烷氧羰基自由基直接诱导的3-氮杂-1,5-二烯与烷基氯xoacetate的级联反应。利用这种方法，在温和的条件下，通过光催化3-叠氮-1,5-二烯烷氧羰基化/环化合成了广泛的含酯吡咯啉-2-酮。此外，脱氢芳构化可以在相同的光催化体系中进行。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Photocatalytic Regioselective Alkoxycarbonylation/Cyclization of 3-Aza-1,5-dienes: Access to Ester-Containing Pyrrolin-2-ones

查看原文本刊更多论文

Photocatalytic Regioselective Alkoxycarbonylation/Cyclization of 3-Aza-1,5-dienes: Access to Ester-Containing Pyrrolin-2-ones

A direct alkoxycarbonyl radical-induced cascade reaction of 3-aza-1,5-dienes with alkyl chlorooxoacetates is reported. With this approach, an extensive range of ester-containing pyrrolin-2-ones are synthesized through photocatalyzed alkoxycarbonylation/cyclization with 3-aza-1,5-dienes under mild conditions. Moreover, dehydrogenative aromatization can proceed with the same photocatalytic system.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.