乙烯基硼酯与芳酰氯自由基氢化反应制备β-硼基酮的研究

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-03-26 DOI:10.1021/acs.orglett.5c00996

Shuai Tang, Shuting Wang, Hua Zhang

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引用次数: 0

摘要

在可见光诱导下，乙烯基硼酯与芳酰氯发生自由基氢化芳基化反应，得到了多种产率中高、官能团耐受性广的β-硼基酮。这种无金属的转化为从现成的芳酰氯和乙烯基硼酯中获得有价值的β-硼基酮提供了方便和实用的途径。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Visible-Light-Induced Radical Hydroaroylation of Vinyl Boronic Ester with Aroyl Chlorides to Access β-Boryl Ketones

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Visible-Light-Induced Radical Hydroaroylation of Vinyl Boronic Ester with Aroyl Chlorides to Access β-Boryl Ketones

A visible-light-induced radical hydroaroylation of vinyl boronic ester with aroyl chlorides has been developed, yielding a variety of β-boryl ketones in moderate to good yields with broad functional group tolerance. This metal-free transformation offers a convenient and practical route to access valuable β-boryl ketones from readily available aroyl chlorides and vinyl boronic ester.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.