关于 "托萘酯在 283.15 K 至 328.15 K 的十种单溶剂和二元溶剂体系中的溶解度测定、相关性、溶剂效应和热力学性质 "的评论

IF 2.2 3区工程技术 Q3 CHEMISTRY, PHYSICAL

Journal of Chemical Thermodynamics Pub Date : 2025-03-22 DOI:10.1016/j.jct.2025.107484

Allison Kabin, Dhishithaa Kumarandurai, Bradley Lin, William E. Acree

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Comments on “solubility determination, correlation, solvent effect and thermodynamic properties of tolnaftate in ten mono-solvents and binary solvent systems from 283.15 K to 328.15 K"

A polemic is given regarding the solution models used by Wang and coworkers to correlate the solubility behavior of tolnaftate in ten organic mono-solvents and in binary acetic acid + ethylene glycol solvent mixtures. For several of the mixtures studied authors' calculated curve-fit parameters yielded mole fraction solubilities that exceeded unity.

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来源期刊

Journal of Chemical Thermodynamics 工程技术-热力学

CiteScore

5.60

自引率

15.40%

发文量

199

审稿时长

79 days

期刊介绍： The Journal of Chemical Thermodynamics exists primarily for dissemination of significant new knowledge in experimental equilibrium thermodynamics and transport properties of chemical systems. The defining attributes of The Journal are the quality and relevance of the papers published. The Journal publishes work relating to gases, liquids, solids, polymers, mixtures, solutions and interfaces. Studies on systems with variability, such as biological or bio-based materials, gas hydrates, among others, will also be considered provided these are well characterized and reproducible where possible. Experimental methods should be described in sufficient detail to allow critical assessment of the accuracy claimed. Authors are encouraged to provide physical or chemical interpretations of the results. Articles can contain modelling sections providing representations of data or molecular insights into the properties or transformations studied. Theoretical papers on chemical thermodynamics using molecular theory or modelling are also considered. The Journal welcomes review articles in the field of chemical thermodynamics but prospective authors should first consult one of the Editors concerning the suitability of the proposed review. Contributions of a routine nature or reporting on uncharacterised materials are not accepted.