硝酸和弱垂直于表面的非均相磁场对用于植入物的AISI 316L奥氏体不锈钢在氯化物溶液中的腐蚀行为的影响

IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING
Djedjiga Ben Abdesselam, Nacer Zazi, Fatah Hellal, Mărioara Abrudeanu, Denis Negrea, Jean Paul Chopart
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引用次数: 0

摘要

研究了在65 wt %的加气硝酸溶液(PCTNA)中进行化学处理,以及垂直于表面的弱永久非均相磁场(WPHMFP)对AISI 316L合金在含0.1wt %葡萄糖的0.9 wt % NaCl溶液中腐蚀行为的影响。PCTNA与在氯溶液中浸泡期间减少局部腐蚀的耦合。PCTNA在无磁场的情况下诱导表面生成Al2O3和SiO2氧化物,在WPHMFP存在的情况下诱导表面生成含氮Al2O3。在静电位和电流电位测试中,WPHMFP的存在使静电位升高,抵消了静电位曲线在硝酸溶液中浸泡前4 h的电化学噪声(EN),消除了极化曲线阳极域的EN,消除了浸泡1 h后极化测试后观察到的晶间腐蚀,减少了局部腐蚀。在硝酸溶液中浸泡3天后,WPHMFP的影响几乎消失。经过化学处理后,在有或无磁场的氯溶液中腐蚀,以及在有磁场的氯溶液中腐蚀而未经化学处理,会导致AgCl从Ag/AgCl参比电极中溶解后在AISI 316L合金表面沉积。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Effects of Prior Chemical Treatment in a Nitric Acid, and a Weak Perpendicular to the Surface Heterogeneous Magnetic Field on the Corrosion behavior of AISI 316L Austenitic Stainless Steel, Intended for Use as an Implant, in Chloride Solution

Effects of Prior Chemical Treatment in a Nitric Acid, and a Weak Perpendicular to the Surface Heterogeneous Magnetic Field on the Corrosion behavior of AISI 316L Austenitic Stainless Steel, Intended for Use as an Implant, in Chloride Solution

Prior chemical treatment in an aerated 65 wt % nitric acid solution (PCTNA), and weak permanent heterogeneous magnetic fields perpendicular to the surface WPHMFP effects on corrosion behavior of AISI 316L alloy in immersion in 0.9 wt % NaCl containing 0.1wt % glucose solution, proposed to use as an implant, have been studied. A PCTNA coupled with reduces localized corrosion during the immersion in a chloride solution. A PCTNA induces the formation of Al2O3 and SiO2 oxides on the surface in absence of magnetic field and Al2O3 containing nitrogen in presence of WPHMFP. The corrosion in the presence WPHMFP during the rest potential and current–potential test increases the rest potential, and cancels the electrochemical noise (EN) on the rest potential curve during the first 4 h of immersion in nitric acid solution, withdraws the EN in anodic domain of polarization curves, remove the intergranular corrosion observed after polarization test following the first hour of immersion, and reduces the localized corrosion. The WPHMFP effects are almost removed after 3 days of immersion in nitric acid solution. The corrosion in chloride solution, after chemical treatment in the presence or in the absence of magnetic field, and the corrosion in a chloride solution in presence of magnetic field and without prior chemical treatment induce AgCl deposition on the surface of AISI 316L alloy after its dissolution from the Ag/AgCl reference electrode.

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来源期刊
CiteScore
1.90
自引率
18.20%
发文量
90
审稿时长
4-8 weeks
期刊介绍: Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.
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