Wenbin Hu, Qiang Yang, Renjuan Wang, Qi Chen, Yun Kong
{"title":"MOF-525 对两种阴离子染料(甲基橙和甲基红)的高效吸附去除:吸附等温线和动力学研究","authors":"Wenbin Hu, Qiang Yang, Renjuan Wang, Qi Chen, Yun Kong","doi":"10.1002/ep.14543","DOIUrl":null,"url":null,"abstract":"<p>Adsorption is widely used to remove anionic and cationic dyes from wastewater because of its economical and high efficiency. Metal-organic frameworks (MOFs), as a kind of adsorbent, have attracted great attention due to the large surface area, adjustable pore size, and high stability. In this study, a Zr-MOF, named MOF-525, was synthesized by using solvothermal method, and the adsorption performances of MOF-525 on two anionic dyes (methyl orange, MO and methyl red, MR) were investigated. Results showed that the obtained MOF-525, with the specific surface area of 2,613.91 m<sup>2</sup> g<sup>−1</sup>, the total pore volume of 1.20 cm<sup>3</sup> g<sup>−1</sup>, and the average pore size of 1.84 nm, exhibited high adsorption capacities for both MO and MR. The optimal pH value for MO and MR adsorption were 3.0 and 4.0, with the adsorption capacity of 854.30 and 629.67 mg g<sup>−1</sup>, respectively; in addition, the adsorption capacities for both MR and MO were increased with the increasing of SO<sub>4</sub><sup>2−</sup> concentration. The adsorption kinetics, isotherms, and thermodynamics results indicated the pseudo-second-order model and Langmuir (as well as Freundlich) could describe the adsorption processes of MOF-525 well, and the adsorption processes for both MO and MR were spontaneous exothermic reactions. Besides, the reusability experiment demonstrated that MOF-525 had significant adsorption capacity and good reusability for MR. In conclusion, the possible adsorption mechanisms of anionic dyes by MOF-525 involved hydrogen bonding, electrostatic attraction, and π-π interaction. These results illustrated that MOF-525 might be a potential adsorption material for anionic dyes removal from wastewater.</p>","PeriodicalId":11701,"journal":{"name":"Environmental Progress & Sustainable Energy","volume":"44 2","pages":""},"PeriodicalIF":2.1000,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Efficient adsorptive removal of two anionic dyes (methyl orange and methyl red) with MOF-525: Adsorption isotherms and kinetics studies\",\"authors\":\"Wenbin Hu, Qiang Yang, Renjuan Wang, Qi Chen, Yun Kong\",\"doi\":\"10.1002/ep.14543\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Adsorption is widely used to remove anionic and cationic dyes from wastewater because of its economical and high efficiency. Metal-organic frameworks (MOFs), as a kind of adsorbent, have attracted great attention due to the large surface area, adjustable pore size, and high stability. In this study, a Zr-MOF, named MOF-525, was synthesized by using solvothermal method, and the adsorption performances of MOF-525 on two anionic dyes (methyl orange, MO and methyl red, MR) were investigated. Results showed that the obtained MOF-525, with the specific surface area of 2,613.91 m<sup>2</sup> g<sup>−1</sup>, the total pore volume of 1.20 cm<sup>3</sup> g<sup>−1</sup>, and the average pore size of 1.84 nm, exhibited high adsorption capacities for both MO and MR. The optimal pH value for MO and MR adsorption were 3.0 and 4.0, with the adsorption capacity of 854.30 and 629.67 mg g<sup>−1</sup>, respectively; in addition, the adsorption capacities for both MR and MO were increased with the increasing of SO<sub>4</sub><sup>2−</sup> concentration. The adsorption kinetics, isotherms, and thermodynamics results indicated the pseudo-second-order model and Langmuir (as well as Freundlich) could describe the adsorption processes of MOF-525 well, and the adsorption processes for both MO and MR were spontaneous exothermic reactions. Besides, the reusability experiment demonstrated that MOF-525 had significant adsorption capacity and good reusability for MR. In conclusion, the possible adsorption mechanisms of anionic dyes by MOF-525 involved hydrogen bonding, electrostatic attraction, and π-π interaction. These results illustrated that MOF-525 might be a potential adsorption material for anionic dyes removal from wastewater.</p>\",\"PeriodicalId\":11701,\"journal\":{\"name\":\"Environmental Progress & Sustainable Energy\",\"volume\":\"44 2\",\"pages\":\"\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-12-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Progress & Sustainable Energy\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ep.14543\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Progress & Sustainable Energy","FirstCategoryId":"93","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ep.14543","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Efficient adsorptive removal of two anionic dyes (methyl orange and methyl red) with MOF-525: Adsorption isotherms and kinetics studies
Adsorption is widely used to remove anionic and cationic dyes from wastewater because of its economical and high efficiency. Metal-organic frameworks (MOFs), as a kind of adsorbent, have attracted great attention due to the large surface area, adjustable pore size, and high stability. In this study, a Zr-MOF, named MOF-525, was synthesized by using solvothermal method, and the adsorption performances of MOF-525 on two anionic dyes (methyl orange, MO and methyl red, MR) were investigated. Results showed that the obtained MOF-525, with the specific surface area of 2,613.91 m2 g−1, the total pore volume of 1.20 cm3 g−1, and the average pore size of 1.84 nm, exhibited high adsorption capacities for both MO and MR. The optimal pH value for MO and MR adsorption were 3.0 and 4.0, with the adsorption capacity of 854.30 and 629.67 mg g−1, respectively; in addition, the adsorption capacities for both MR and MO were increased with the increasing of SO42− concentration. The adsorption kinetics, isotherms, and thermodynamics results indicated the pseudo-second-order model and Langmuir (as well as Freundlich) could describe the adsorption processes of MOF-525 well, and the adsorption processes for both MO and MR were spontaneous exothermic reactions. Besides, the reusability experiment demonstrated that MOF-525 had significant adsorption capacity and good reusability for MR. In conclusion, the possible adsorption mechanisms of anionic dyes by MOF-525 involved hydrogen bonding, electrostatic attraction, and π-π interaction. These results illustrated that MOF-525 might be a potential adsorption material for anionic dyes removal from wastewater.
期刊介绍:
Environmental Progress , a quarterly publication of the American Institute of Chemical Engineers, reports on critical issues like remediation and treatment of solid or aqueous wastes, air pollution, sustainability, and sustainable energy. Each issue helps chemical engineers (and those in related fields) stay on top of technological advances in all areas associated with the environment through feature articles, updates, book and software reviews, and editorials.