{"title":"磁性纳米吸附剂对桉树提取物镉的吸附研究","authors":"Ezzat Azari, Mahmood Niad","doi":"10.1016/j.poly.2025.117497","DOIUrl":null,"url":null,"abstract":"<div><div>This study aimed to evaluate the removal of cadmium using a magnetic nano sorbent derived from Eucalyptus extract. The sorbent was characterized by X-ray diffraction analysis, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, vibrating sample magnetometer, and Fourier-transform infrared spectroscopy. Factors affecting Cd uptake, including pH, initial Cd concentration, temperature, and contact time, were studied. Response surface methodology and an adaptive network-based fuzzy inference system were employed to predict the optimum conditions for cadmium adsorption. Various models were used to fit the kinetic experimental data, and thermodynamic variables were calculated.</div></div>","PeriodicalId":20278,"journal":{"name":"Polyhedron","volume":"274 ","pages":"Article 117497"},"PeriodicalIF":2.4000,"publicationDate":"2025-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Cadmium uptake by magnetic nano sorbent on Eucalyptus extract\",\"authors\":\"Ezzat Azari, Mahmood Niad\",\"doi\":\"10.1016/j.poly.2025.117497\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study aimed to evaluate the removal of cadmium using a magnetic nano sorbent derived from Eucalyptus extract. The sorbent was characterized by X-ray diffraction analysis, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, vibrating sample magnetometer, and Fourier-transform infrared spectroscopy. Factors affecting Cd uptake, including pH, initial Cd concentration, temperature, and contact time, were studied. Response surface methodology and an adaptive network-based fuzzy inference system were employed to predict the optimum conditions for cadmium adsorption. Various models were used to fit the kinetic experimental data, and thermodynamic variables were calculated.</div></div>\",\"PeriodicalId\":20278,\"journal\":{\"name\":\"Polyhedron\",\"volume\":\"274 \",\"pages\":\"Article 117497\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2025-03-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polyhedron\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0277538725001111\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polyhedron","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0277538725001111","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Cadmium uptake by magnetic nano sorbent on Eucalyptus extract
This study aimed to evaluate the removal of cadmium using a magnetic nano sorbent derived from Eucalyptus extract. The sorbent was characterized by X-ray diffraction analysis, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, vibrating sample magnetometer, and Fourier-transform infrared spectroscopy. Factors affecting Cd uptake, including pH, initial Cd concentration, temperature, and contact time, were studied. Response surface methodology and an adaptive network-based fuzzy inference system were employed to predict the optimum conditions for cadmium adsorption. Various models were used to fit the kinetic experimental data, and thermodynamic variables were calculated.
期刊介绍:
Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry.
Papers should be significant pieces of work, and all new compounds must be appropriately characterized. The inclusion of single-crystal X-ray structural data is strongly encouraged, but papers reporting only the X-ray structure determination of a single compound will usually not be considered. Papers on solid-state or materials chemistry will be expected to have a significant molecular chemistry component (such as the synthesis and characterization of the molecular precursors and/or a systematic study of the use of different precursors or reaction conditions) or demonstrate a cutting-edge application (for example inorganic materials for energy applications). Papers dealing only with stability constants are not considered.