稳定土核中全氟烷基和多氟烷基物质(PFAS)的红外基质辅助激光解吸电喷雾电离(IR-MALDESI)质谱成像

IF 3.1 2区 化学 Q2 BIOCHEMICAL RESEARCH METHODS
Theresa Guillette, Whitney Stutts, Andrew Baumeister, David Liles, Theresa Olechiw, Johnsie Lang
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引用次数: 0

摘要

红外基质辅助激光解吸电喷雾电离(IR-MALDESI)与高分辨率精确质谱联用(HRAM-MS)相结合,对稳定土岩心中的全氟烷基和多氟烷基物质(PFAS)进行了成像。先前的现场规模研究表明,在水成膜泡沫(AFFF)源区应用原位稳定和凝固(S/S)后,PFAS的浸出能力大幅下降。虽然先前的研究经验证实了S/S的有效性,但对手术保留机制没有明确的认识。因此,这项后续研究的目标是:(1)开发一种基于高分辨率质谱的成像技术,用于稳定和背景对照土芯上的PFAS;(2)在微米尺度上确定修正物的化学特征是否与土芯内PFAS的空间分布有关。完整的冻土岩心在负离子模式下成像,进行靶向和可疑筛选分析,使用可疑列表识别特征,并将分析物作为原始丰度与多个数据库进行匹配。IR-MALDESI成像结果证实了PFOS和PFHxS与非PFAS化学特征(如单甘油酯和双甘油酯)的共存,这些特征与包括修正在内的处理有关,这表明化学固定是稳定土芯中PFAS稳定的一种机制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Infrared Matrix-Assisted Laser Desorption Electrospray Ionization (IR-MALDESI) Mass Spectrometry Imaging of Per- and Polyfluoroalkyl Substances (PFAS) in Stabilized Soil Cores.

Infrared matrix-assisted laser desorption electrospray ionization (IR-MALDESI) was coupled with high-resolution accurate-mass-mass spectrometry (HRAM-MS) to image perfluoroalkyl and polyfluoroalkyl substances (PFAS) in stabilized soil cores. Previous field-scale research demonstrated a substantial decrease in the leachability of PFAS following the application of in situ stabilization and solidification (S/S) in an aqueous film-forming foam (AFFF) source zone. While this previous study empirically confirmed the effectiveness of S/S, there was no definitive identification of the operative retention mechanisms. Therefore, the objective of this follow-on study was to (1) develop a high-resolution mass spectrometry-based imaging technique for PFAS on stabilized and background control soil cores and (2) determine if chemical characteristics of the amendments were associated spatially with the PFAS distribution within the soil cores at a micrometer scale. Intact frozen soil cores were imaged in negative ion mode, targeted and suspect screening analyses were conducted, features were identified using suspect lists, and analytes were presented as raw abundances matched against several databases. IR-MALDESI imaging results confirmed the colocation of PFOS and PFHxS with non-PFAS chemical features (e.g., mono- and diglycerides) associated with treatments including amendments, which suggests chemical fixation as a mechanism of stabilization for PFAS in stabilized soil cores.

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来源期刊
CiteScore
5.50
自引率
9.40%
发文量
257
审稿时长
1 months
期刊介绍: The Journal of the American Society for Mass Spectrometry presents research papers covering all aspects of mass spectrometry, incorporating coverage of fields of scientific inquiry in which mass spectrometry can play a role. Comprehensive in scope, the journal publishes papers on both fundamentals and applications of mass spectrometry. Fundamental subjects include instrumentation principles, design, and demonstration, structures and chemical properties of gas-phase ions, studies of thermodynamic properties, ion spectroscopy, chemical kinetics, mechanisms of ionization, theories of ion fragmentation, cluster ions, and potential energy surfaces. In addition to full papers, the journal offers Communications, Application Notes, and Accounts and Perspectives
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