膨润土与dehpa改性膨润土增强ABS复合材料的力学、热、形态性能研究

IF 3.9 3区 化学 Q2 POLYMER SCIENCE
İdris Karagöz, B. Şebnem Şimşiroğlu, Elif Nur Özer, Harun Sepetcioglu, Jülide Hızal
{"title":"膨润土与dehpa改性膨润土增强ABS复合材料的力学、热、形态性能研究","authors":"İdris Karagöz,&nbsp;B. Şebnem Şimşiroğlu,&nbsp;Elif Nur Özer,&nbsp;Harun Sepetcioglu,&nbsp;Jülide Hızal","doi":"10.1002/pol.20240925","DOIUrl":null,"url":null,"abstract":"<p>This study investigates the mechanical, thermal, and surface characteristics of acrylonitrile–butadiene–styrene (ABS) composites reinforced with bentonite and bis(2-ethylhexyl) phosphate (DEHPA)-modified bentonite. The addition of bentonite significantly reduced the tensile strength and elongation at break due to the filler's inherent brittleness. Pure ABS exhibited a tensile strength of 42.2 MPa, which decreased by 16.1% with the incorporation of 20% bentonite (ABS1). Impact strength tests showed that the inclusion of bentonite lowered impact resistance, particularly in notched samples. Bentonite also increased the hardness and density, reflecting improved rigidity but reduced flexibility. Surface gloss changed from semigloss to matte, and FT-IR spectroscopy confirmed the successful integration of bentonite. Water absorption tests revealed that DEHPA-modified bentonite composites had higher absorption over time, highlighting the modification's effect on hydrophilicity. While bentonite improves certain properties, the balance between mechanical strength and flexibility needs to be further explored to meet the requirements of specific applications such as automotive components, electronics casings, and construction materials.</p>","PeriodicalId":16888,"journal":{"name":"Journal of Polymer Science","volume":"63 6","pages":"1505-1517"},"PeriodicalIF":3.9000,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pol.20240925","citationCount":"0","resultStr":"{\"title\":\"Investigation of the Mechanical, Thermal, and Morphological Properties of ABS Composite Reinforced With Bentonite and DEHPA-Modified Bentonite\",\"authors\":\"İdris Karagöz,&nbsp;B. Şebnem Şimşiroğlu,&nbsp;Elif Nur Özer,&nbsp;Harun Sepetcioglu,&nbsp;Jülide Hızal\",\"doi\":\"10.1002/pol.20240925\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study investigates the mechanical, thermal, and surface characteristics of acrylonitrile–butadiene–styrene (ABS) composites reinforced with bentonite and bis(2-ethylhexyl) phosphate (DEHPA)-modified bentonite. The addition of bentonite significantly reduced the tensile strength and elongation at break due to the filler's inherent brittleness. Pure ABS exhibited a tensile strength of 42.2 MPa, which decreased by 16.1% with the incorporation of 20% bentonite (ABS1). Impact strength tests showed that the inclusion of bentonite lowered impact resistance, particularly in notched samples. Bentonite also increased the hardness and density, reflecting improved rigidity but reduced flexibility. Surface gloss changed from semigloss to matte, and FT-IR spectroscopy confirmed the successful integration of bentonite. Water absorption tests revealed that DEHPA-modified bentonite composites had higher absorption over time, highlighting the modification's effect on hydrophilicity. While bentonite improves certain properties, the balance between mechanical strength and flexibility needs to be further explored to meet the requirements of specific applications such as automotive components, electronics casings, and construction materials.</p>\",\"PeriodicalId\":16888,\"journal\":{\"name\":\"Journal of Polymer Science\",\"volume\":\"63 6\",\"pages\":\"1505-1517\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2025-02-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/pol.20240925\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/pol.20240925\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/pol.20240925","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

摘要

本研究研究了膨润土和二(2-乙基己基)磷酸(DEHPA)改性膨润土增强丙烯腈-丁二烯-苯乙烯(ABS)复合材料的力学、热学和表面特性。膨润土的加入显著降低了抗拉强度和断裂伸长率,这是由于填料固有的脆性。纯ABS的抗拉强度为42.2 MPa,添加20%的膨润土(ABS1)后,ABS的抗拉强度下降16.1%。冲击强度试验表明,膨润土的加入降低了试样的抗冲击性,尤其是有缺口的试样。膨润土也增加了硬度和密度,反映了刚性的提高,但灵活性的降低。表面光泽度由半光泽变为哑光,红外光谱证实了膨润土的成功整合。吸水试验表明,dehpa改性膨润土复合材料随着时间的推移具有更高的吸水性,突出了改性对亲水性的影响。虽然膨润土提高了某些性能,但需要进一步探索机械强度和柔韧性之间的平衡,以满足汽车零部件、电子外壳和建筑材料等特定应用的要求。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Investigation of the Mechanical, Thermal, and Morphological Properties of ABS Composite Reinforced With Bentonite and DEHPA-Modified Bentonite

Investigation of the Mechanical, Thermal, and Morphological Properties of ABS Composite Reinforced With Bentonite and DEHPA-Modified Bentonite

This study investigates the mechanical, thermal, and surface characteristics of acrylonitrile–butadiene–styrene (ABS) composites reinforced with bentonite and bis(2-ethylhexyl) phosphate (DEHPA)-modified bentonite. The addition of bentonite significantly reduced the tensile strength and elongation at break due to the filler's inherent brittleness. Pure ABS exhibited a tensile strength of 42.2 MPa, which decreased by 16.1% with the incorporation of 20% bentonite (ABS1). Impact strength tests showed that the inclusion of bentonite lowered impact resistance, particularly in notched samples. Bentonite also increased the hardness and density, reflecting improved rigidity but reduced flexibility. Surface gloss changed from semigloss to matte, and FT-IR spectroscopy confirmed the successful integration of bentonite. Water absorption tests revealed that DEHPA-modified bentonite composites had higher absorption over time, highlighting the modification's effect on hydrophilicity. While bentonite improves certain properties, the balance between mechanical strength and flexibility needs to be further explored to meet the requirements of specific applications such as automotive components, electronics casings, and construction materials.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Polymer Science
Journal of Polymer Science POLYMER SCIENCE-
CiteScore
6.30
自引率
5.90%
发文量
264
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信