MgO在低浓度石油污染土壤修复中的高效吸附、包封和稳定作用。

IF 3.2 3区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL
Yin Wang, Jiao Zhao, Xiaojia Tang, Tie Li, Yang Liu, Yimin Zhu
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引用次数: 0

摘要

石油污染土壤具有复杂的性质和成分,严重危害环境,治理难度大。本研究提出了一种以MgO为修复剂修复PCS的新方法。同时,通过各种表征方法揭示了PCS修复的机理。研究发现MgO对PCS有较好的修复效果。PCS修复结果表明,在最佳修复条件下,PCS的残油率由2.62%降至1.37%,修复后PCS的绝对去除率为37.3%。机理研究表明,在煅烧温度为650℃、煅烧时间为120 min、升温速率为10℃/min的条件下,制备的MgO具有比表面积大、水化活性高、吸附能力强的特点。在PCS的修复过程中,MgO被紧密吸附在PCS颗粒表面,与水接触后迅速发生水化反应生成Mg(OH)2。Mg(OH)2能有效地将土壤颗粒包裹牢固,保证了PCS的稳定性,从而实现对PCS的有效修复。本研究为低浓度PCS的修复提供了一种新的方法,对今后低浓度PCS的深度处理研究具有重要的科学意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Efficient adsorption, encapsulation and stabilization of MgO in the remediation of low-concentration petroleum contaminated soil.

Petroleum contaminated soil (PCS) has complex properties and compositions, which seriously endangers the environment and is difficult to treat. In this study, a new method for the remediation of PCS using MgO as remediation agent was proposed. Meanwhile, the mechanism of PCS remediation was revealed by various characterization methods. The study found that MgO was effective in remediating PCS. The results of PCS remediation showed that the residual oil rate of PCS decreased from 2.62 to 1.37%, and the absolute removal rate of oil in PCS after remediation was 37.3% under the optimum remediation conditions. The mechanism research indicated that the prepared MgO had large specific surface area, high hydration activity and strong adsorption with the conditions of calcination temperature of 650°C, calcination time of 120 min and heating rate of 10°C/min. In the remediation process of PCS, MgO was tightly adsorbed on the surface of PCS particles, and the hydration reaction occurred rapidly after contact with water to form Mg(OH)2. Mg(OH)2 could effectively encapsulate soil particles firmly, ensuring the stability of PCS, thereby achieving the effective remediation of PCS. This study provided a new method for the remediation of low-concentration PCS, and had important scientific significance for the future research on the advanced treatment of low-concentration PCS.

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来源期刊
Environmental Geochemistry and Health
Environmental Geochemistry and Health 环境科学-工程:环境
CiteScore
8.00
自引率
4.80%
发文量
279
审稿时长
4.2 months
期刊介绍: Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people. Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes. The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.
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