高效低价钨催化的叔胺与蒎烯硼烷脱氧还原制胺

Organic chemistry frontiers : an international journal of organic chemistry Pub Date : 2025-03-03 DOI:10.1039/d4qo02340d

Biao Cheng , Jialong Xv , Xiang Ren , Yuanyuan Li , Xiaoming Ji , Zhan Lu

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引用次数: 0

摘要

研究了一种高效的低价钨催化双氯硼烷（HBpin）对叔胺的脱氧还原反应。该方案使用市售的W(CO)6作为催化剂，在不含其他添加剂的情况下，在可见光照射下的己烷溶液中进行，TON可达2000。

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Highly efficient low-valence tungsten-catalyzed deoxygenative reduction of tertiary amides to amines with pinacolborane†

A highly efficient low-valence tungsten-catalyzed deoxygenative reduction of tertiary amides to amines with pinacolborane (HBPin) is developed. This protocol uses commercially available W(CO)₆ as a catalyst in a solution of hexane under the irradiation of visible light without other additives, and the TON is up to 2000.

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来源期刊

Organic chemistry frontiers : an international journal of organic chemistry

CiteScore

7.80

自引率

0.00%

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