沸石组成的多孔吸附剂储氢性能研究

IF 1.204 Q3 Energy
M. S. Paizullakhanov, O. R. Parpiev, Zh. Z. Shermatov, E. Z. Nodirmatov, O. T. Rajamatov
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引用次数: 0

摘要

研究了多孔陶瓷材料的吸氢过程。介绍了用于吸氢器的多孔材料的合成结果。得到了吸氢程度与吸收剂的组成以及吸氢温度的关系。结果表明,在高(30-50大气压)压力下,由比表面积为2500 cm2/g的太阳炉熔合原料合成的硅酸铝材料可作为吸氢剂,通过范德瓦尔兹力使氢在孔隙中物理结合。结果表明,在200℃下,材料吸收氢的能力随组合物的不同而不同。长径数的最大值(4.3 wt %)对应于硅藻土含量为70 wt %和燃尽添加剂重量为20%的材料。结果表明,晶格参数a = 4.056 А的AlSiNaO铝硅酸钠多孔材料是一种良好的吸氢材料。随着吸附过程温度从100°C增加到190°C,截面数的值从3wt %增加到13wt %。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Hydrogen Storage on Porous Absorbers with a Zeolite Composition

Hydrogen Storage on Porous Absorbers with a Zeolite Composition

The processes of hydrogen absorption in porous ceramic materials have been studied. The results of the synthesis of porous materials for use in hydrogen absorbers are presented. The dependences of the degree of hydrogen absorption on the composition of the absorber, as well as on the temperature of hydrogen sorption, are obtained. It is shown that aluminosilicate materials synthesized from raw materials fused in a solar furnace with a specific surface area of 2500 cm2/g can be used as hydrogen absorbers for the physical binding of hydrogen in pores by Van der Waltz forces at high (30–50 atm) pressures. It was revealed that the aspect number, i.e., the ability of the material to absorb hydrogen at 200°C, varies from composition to composition. The maximum value of the aspect number (4.3 wt %) corresponds to a material with a diatomite content of 70 wt % and burnout additives of 20% by weight. It is shown that a porous material based on AlSiNaO sodium aluminosilicate with lattice parameter a = 4.056 А is a good hydrogen absorber. With an increase in the temperature of the sorption process from 100 to 190°C, the value of the aspect number increases from 3 wt % up to 13 wt %.

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来源期刊
Applied Solar Energy
Applied Solar Energy Energy-Renewable Energy, Sustainability and the Environment
CiteScore
2.50
自引率
0.00%
发文量
0
期刊介绍: Applied Solar Energy  is an international peer reviewed journal covers various topics of research and development studies on solar energy conversion and use: photovoltaics, thermophotovoltaics, water heaters, passive solar heating systems, drying of agricultural production, water desalination, solar radiation condensers, operation of Big Solar Oven, combined use of solar energy and traditional energy sources, new semiconductors for solar cells and thermophotovoltaic system photocells, engines for autonomous solar stations.
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