Elias Sebti, Hayden A. Evans, Hengning Chen, Peter M. Richardson, Kelly M. White, Raynald Giovine, Krishna Prasad Koirala, Yaobin Xu, Eliovardo Gonzalez-Correa, Chongmin Wang, Craig M. Brown, Anthony K. Cheetham, Pieremanuele Canepa, Raphaële J. Clément
{"title":"修正“层错有助于卤化物基超离子导体中锂离子的传导”","authors":"Elias Sebti, Hayden A. Evans, Hengning Chen, Peter M. Richardson, Kelly M. White, Raynald Giovine, Krishna Prasad Koirala, Yaobin Xu, Eliovardo Gonzalez-Correa, Chongmin Wang, Craig M. Brown, Anthony K. Cheetham, Pieremanuele Canepa, Raphaële J. Clément","doi":"10.1021/jacs.5c02447","DOIUrl":null,"url":null,"abstract":"<b>Summary of corrections:</b> A typographical error needs to be corrected in the Results section, subsection “2.5. Evaluation of Li<sup>+</sup> Ion Conduction Properties”, fourth paragraph, where the activation energy barriers derived from PFG-NMR were swapped for components 1 and 2, for both BM-LYC and SS-LYC. The same error should also corrected in the second paragraph of the Discussion section. <b>Page 5804, left column:</b> “The derived activation energies for ion migration in BM-LYC are 0.25 ± 0.01 eV and 0.18 ± 0.03 eV (all confidence intervals listed are 1σ) for components 1 and 2, respectively. For SS-LYC, these are 0.57 ± 0.09 eV and 0.48 ± 0.1 eV.” The new version should read: “The derived activation energies for ion migration in BM-LYC are 0.18 ± 0.03 eV and 0.25 ± 0.01 eV (all confidence intervals listed are 1σ) for components 1 and 2, respectively. For SS-LYC, these are 0.48 ± 0.1 eV and 0.57 ± 0.09 eV.” <b>This error propagates in the second paragraph of the Discussion section, page 5805, left column:</b> “Since <i>c</i>-axis conduction usually has a lower migration barrier, component 1 is assigned to diffusion along the <i>c</i>-axis and component 2 to <i>ab</i>-plane diffusion. For the ball milled sample, both components exhibit much lower activation energy barriers than that of bulk Li<sup>+</sup> conduction measured by EIS (0.25 ± 0.01 eV and 0.18 ± 0.03 eV vs 0.41 ± 0.006 eV).” The correct version is “Since <i>c</i>-axis conduction usually has a lower migration barrier, component 1 is assigned to diffusion along the <i>c</i>-axis and component 2 to <i>ab</i>-plane diffusion. For the ball milled sample, both components exhibit much lower activation energy barriers than that of bulk Li<sup>+</sup> conduction measured by EIS (0.18 ± 0.03 eV and 0.25 ± 0.01 eV vs 0.41 ± 0.006 eV).” The conclusions of the study are not affected by these changes. This article has not yet been cited by other publications.","PeriodicalId":49,"journal":{"name":"Journal of the American Chemical Society","volume":"33 1","pages":""},"PeriodicalIF":15.6000,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Correction to “Stacking Faults Assist Lithium-Ion Conduction in a Halide-Based Superionic Conductor”\",\"authors\":\"Elias Sebti, Hayden A. Evans, Hengning Chen, Peter M. Richardson, Kelly M. White, Raynald Giovine, Krishna Prasad Koirala, Yaobin Xu, Eliovardo Gonzalez-Correa, Chongmin Wang, Craig M. Brown, Anthony K. Cheetham, Pieremanuele Canepa, Raphaële J. Clément\",\"doi\":\"10.1021/jacs.5c02447\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<b>Summary of corrections:</b> A typographical error needs to be corrected in the Results section, subsection “2.5. Evaluation of Li<sup>+</sup> Ion Conduction Properties”, fourth paragraph, where the activation energy barriers derived from PFG-NMR were swapped for components 1 and 2, for both BM-LYC and SS-LYC. The same error should also corrected in the second paragraph of the Discussion section. <b>Page 5804, left column:</b> “The derived activation energies for ion migration in BM-LYC are 0.25 ± 0.01 eV and 0.18 ± 0.03 eV (all confidence intervals listed are 1σ) for components 1 and 2, respectively. For SS-LYC, these are 0.57 ± 0.09 eV and 0.48 ± 0.1 eV.” The new version should read: “The derived activation energies for ion migration in BM-LYC are 0.18 ± 0.03 eV and 0.25 ± 0.01 eV (all confidence intervals listed are 1σ) for components 1 and 2, respectively. For SS-LYC, these are 0.48 ± 0.1 eV and 0.57 ± 0.09 eV.” <b>This error propagates in the second paragraph of the Discussion section, page 5805, left column:</b> “Since <i>c</i>-axis conduction usually has a lower migration barrier, component 1 is assigned to diffusion along the <i>c</i>-axis and component 2 to <i>ab</i>-plane diffusion. For the ball milled sample, both components exhibit much lower activation energy barriers than that of bulk Li<sup>+</sup> conduction measured by EIS (0.25 ± 0.01 eV and 0.18 ± 0.03 eV vs 0.41 ± 0.006 eV).” The correct version is “Since <i>c</i>-axis conduction usually has a lower migration barrier, component 1 is assigned to diffusion along the <i>c</i>-axis and component 2 to <i>ab</i>-plane diffusion. For the ball milled sample, both components exhibit much lower activation energy barriers than that of bulk Li<sup>+</sup> conduction measured by EIS (0.18 ± 0.03 eV and 0.25 ± 0.01 eV vs 0.41 ± 0.006 eV).” The conclusions of the study are not affected by these changes. 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引用次数: 0
摘要
更正摘要:结果 "部分 "2.5.Li+ 离子传导特性的评估 "第 4 段中,BM-LYC 和 SS-LYC 的第 1 和第 2 组分的 PFG-NMR 活化能势垒对调了。同样的错误也应在讨论部分第二段中更正。第 5804 页,左栏:"BM-LYC 中离子迁移的衍生活化能对于成分 1 和 2 分别为 0.25 ± 0.01 eV 和 0.18 ± 0.03 eV(列出的置信区间均为 1σ)。对于 SS-LYC,则分别为 0.57 ± 0.09 eV 和 0.48 ± 0.1 eV。新版本应为"对于成分 1 和 2,BM-LYC 中离子迁移的衍生活化能分别为 0.18 ± 0.03 eV 和 0.25 ± 0.01 eV(列出的置信区间均为 1σ)。对于 SS-LYC,则分别为 0.48 ± 0.1 eV 和 0.57 ± 0.09 eV。这一错误在第 5805 页左栏 "讨论 "部分第二段中传播:"由于 c 轴传导通常具有较低的迁移势垒,因此将分量 1 指定为沿 c 轴的扩散,将分量 2 指定为非平面扩散。对于球磨样品,这两个分量的活化能势垒都比 EIS 测得的块状 Li+ 传导的活化能势垒低得多(0.25 ± 0.01 eV 和 0.18 ± 0.03 eV 与 0.41 ± 0.006 eV 相比)"。正确的版本是 "由于 c 轴传导通常具有较低的迁移势垒,因此将分量 1 指定为沿 c 轴的扩散,将分量 2 指定为非平面扩散。对于球磨样品,这两个分量的活化能势垒都比 EIS 测得的块状 Li+ 传导的活化能势垒低得多(0.18 ± 0.03 eV 和 0.25 ± 0.01 eV 对 0.41 ± 0.006 eV)"。研究结论不受这些变化的影响。本文尚未被其他出版物引用。
Correction to “Stacking Faults Assist Lithium-Ion Conduction in a Halide-Based Superionic Conductor”
Summary of corrections: A typographical error needs to be corrected in the Results section, subsection “2.5. Evaluation of Li+ Ion Conduction Properties”, fourth paragraph, where the activation energy barriers derived from PFG-NMR were swapped for components 1 and 2, for both BM-LYC and SS-LYC. The same error should also corrected in the second paragraph of the Discussion section. Page 5804, left column: “The derived activation energies for ion migration in BM-LYC are 0.25 ± 0.01 eV and 0.18 ± 0.03 eV (all confidence intervals listed are 1σ) for components 1 and 2, respectively. For SS-LYC, these are 0.57 ± 0.09 eV and 0.48 ± 0.1 eV.” The new version should read: “The derived activation energies for ion migration in BM-LYC are 0.18 ± 0.03 eV and 0.25 ± 0.01 eV (all confidence intervals listed are 1σ) for components 1 and 2, respectively. For SS-LYC, these are 0.48 ± 0.1 eV and 0.57 ± 0.09 eV.” This error propagates in the second paragraph of the Discussion section, page 5805, left column: “Since c-axis conduction usually has a lower migration barrier, component 1 is assigned to diffusion along the c-axis and component 2 to ab-plane diffusion. For the ball milled sample, both components exhibit much lower activation energy barriers than that of bulk Li+ conduction measured by EIS (0.25 ± 0.01 eV and 0.18 ± 0.03 eV vs 0.41 ± 0.006 eV).” The correct version is “Since c-axis conduction usually has a lower migration barrier, component 1 is assigned to diffusion along the c-axis and component 2 to ab-plane diffusion. For the ball milled sample, both components exhibit much lower activation energy barriers than that of bulk Li+ conduction measured by EIS (0.18 ± 0.03 eV and 0.25 ± 0.01 eV vs 0.41 ± 0.006 eV).” The conclusions of the study are not affected by these changes. This article has not yet been cited by other publications.
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