{"title":"基于微波辅助溶胶-凝胶工艺制作的掺镉 IGZO 薄膜的加热器嵌入式可见光光电晶体管","authors":"Eun-Ha Kim, Tae-Jun Ha","doi":"10.1002/adom.202402171","DOIUrl":null,"url":null,"abstract":"<p>A phototransistor with a sol–gel-based Cd-doped indium-gallium-zinc-oxide (IGZO) photoactive sensing channel on a dual-purpose indium-tin-oxide (ITO) substrate (gate electrode and embedded transparent heater) is reported for the first time. The Cd-doped IGZO layer is fabricated in situ by a one-step microwave-assisted sol–gel process with reduced temperature (<125 °C) and time (<15 min). Despite the wide bandgap of the IGZO (≈3.83 eV) channel, visible-light (≈2 eV) photosensing is achieved in the developed phototransistor upon Cd doping owing to the reduced bandgap (≈3.71 eV) and increased density of subgap states associated with oxygen vacancies in the metal–oxygen bonding structure. In addition, the Cd-doped IGZO phototransistor exhibits excellent operational stability (up to 10 000 cycles) and long-term reliability (up to 30 days). Finally, the embedded Joule heater, based on the inherent transparent ITO substrate, significantly improves the recovery characteristics of the IGZO phototransistor owing to relaxation of the photoexcited charges at the oxygen-vacancy-related trap states upon heating, resulting in 100% recovery in a significantly reduced timeframe (≈10 s). These findings pave the way for the development of high-performance, stable, and reliable visible-light phototransistors based on wide-bandgap IGZO active sensing channels with fast and full recovery, expanding their practical applicability of optoelectronics.</p>","PeriodicalId":116,"journal":{"name":"Advanced Optical Materials","volume":"13 6","pages":""},"PeriodicalIF":8.0000,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Heater-Embedded Visible-Light Phototransistor Based on Cd-Doped IGZO Film Fabricated through Microwave-Assisted Sol–Gel Process\",\"authors\":\"Eun-Ha Kim, Tae-Jun Ha\",\"doi\":\"10.1002/adom.202402171\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A phototransistor with a sol–gel-based Cd-doped indium-gallium-zinc-oxide (IGZO) photoactive sensing channel on a dual-purpose indium-tin-oxide (ITO) substrate (gate electrode and embedded transparent heater) is reported for the first time. The Cd-doped IGZO layer is fabricated in situ by a one-step microwave-assisted sol–gel process with reduced temperature (<125 °C) and time (<15 min). Despite the wide bandgap of the IGZO (≈3.83 eV) channel, visible-light (≈2 eV) photosensing is achieved in the developed phototransistor upon Cd doping owing to the reduced bandgap (≈3.71 eV) and increased density of subgap states associated with oxygen vacancies in the metal–oxygen bonding structure. In addition, the Cd-doped IGZO phototransistor exhibits excellent operational stability (up to 10 000 cycles) and long-term reliability (up to 30 days). Finally, the embedded Joule heater, based on the inherent transparent ITO substrate, significantly improves the recovery characteristics of the IGZO phototransistor owing to relaxation of the photoexcited charges at the oxygen-vacancy-related trap states upon heating, resulting in 100% recovery in a significantly reduced timeframe (≈10 s). These findings pave the way for the development of high-performance, stable, and reliable visible-light phototransistors based on wide-bandgap IGZO active sensing channels with fast and full recovery, expanding their practical applicability of optoelectronics.</p>\",\"PeriodicalId\":116,\"journal\":{\"name\":\"Advanced Optical Materials\",\"volume\":\"13 6\",\"pages\":\"\"},\"PeriodicalIF\":8.0000,\"publicationDate\":\"2024-11-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Optical Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adom.202402171\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Optical Materials","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adom.202402171","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Heater-Embedded Visible-Light Phototransistor Based on Cd-Doped IGZO Film Fabricated through Microwave-Assisted Sol–Gel Process
A phototransistor with a sol–gel-based Cd-doped indium-gallium-zinc-oxide (IGZO) photoactive sensing channel on a dual-purpose indium-tin-oxide (ITO) substrate (gate electrode and embedded transparent heater) is reported for the first time. The Cd-doped IGZO layer is fabricated in situ by a one-step microwave-assisted sol–gel process with reduced temperature (<125 °C) and time (<15 min). Despite the wide bandgap of the IGZO (≈3.83 eV) channel, visible-light (≈2 eV) photosensing is achieved in the developed phototransistor upon Cd doping owing to the reduced bandgap (≈3.71 eV) and increased density of subgap states associated with oxygen vacancies in the metal–oxygen bonding structure. In addition, the Cd-doped IGZO phototransistor exhibits excellent operational stability (up to 10 000 cycles) and long-term reliability (up to 30 days). Finally, the embedded Joule heater, based on the inherent transparent ITO substrate, significantly improves the recovery characteristics of the IGZO phototransistor owing to relaxation of the photoexcited charges at the oxygen-vacancy-related trap states upon heating, resulting in 100% recovery in a significantly reduced timeframe (≈10 s). These findings pave the way for the development of high-performance, stable, and reliable visible-light phototransistors based on wide-bandgap IGZO active sensing channels with fast and full recovery, expanding their practical applicability of optoelectronics.
期刊介绍:
Advanced Optical Materials, part of the esteemed Advanced portfolio, is a unique materials science journal concentrating on all facets of light-matter interactions. For over a decade, it has been the preferred optical materials journal for significant discoveries in photonics, plasmonics, metamaterials, and more. The Advanced portfolio from Wiley is a collection of globally respected, high-impact journals that disseminate the best science from established and emerging researchers, aiding them in fulfilling their mission and amplifying the reach of their scientific discoveries.