硫代膦烷的合成：一种特殊的膦烯前体

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-02-10 DOI:10.1021/acs.orglett.5c0008410.1021/acs.orglett.5c00084

Chenyong Xu, Yiman Gou, Wenxin Zhang, Rongqiang Tian* and Zheng Duan*,

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引用次数: 0

摘要

通过磷酰化物配合物与硫（或硒）的反应，实现了一种简单方便的合成硫取代（Ch = S或Se）磷酰烷的方法。该方法具有良好的官能团相容性。膦烯上的S（或Se）孤对的环应变和稳定性使这些膦烯成为特殊的膦烯前体。通过P-S （Se）键转移反应，证明了这些硫代膦的合成势。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis of Chalcogen-Substituted Phosphiranes: A Privileged Phosphinidene Precursor

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Synthesis of Chalcogen-Substituted Phosphiranes: A Privileged Phosphinidene Precursor

A simple and convenient method for synthesizing chalcogen-substituted (Ch = S or Se) phosphiranes was achieved through the reaction of a phosphiranide complex with sulfur (or selenium). The presented approach shows a good functional group compatibility. The ring strain and stability of the lone pair of S (or Se) on phosphinidenes enable these phosphiranes to be privileged phosphinidene precursors. The synthetic potentials of these chalcogen-substituted phosphiranes were demonstrated through P–S (Se) bond transfer reactions with various phosphinidene trapping reagents.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.