共价有机多环的设计合成

IF 15.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2025-02-10 DOI:10.1021/jacs.4c1632010.1021/jacs.4c16320

Tong Yang, Qian Gao, Xue-Hui Liu, Jin-Min Wu, Wei Wang and San-Yuan Ding*,

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引用次数: 0

摘要

通过刚性三臂y形和u形构件的共价组装，设计并合成了共价有机多环。这些COMs具有精确的三环结构，在一系列常见溶剂中表现出显著的溶解性。这些COMs具有明确的空腔和富电子结构，对碘在蒸汽和液体状态下都表现出良好的吸附能力。此外，溶液可加工性允许通过自旋涂层方法在不同基材上方便地制造这些COMs作为均匀薄膜。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Designed Synthesis of Covalent Organic Multicycles

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Designed Synthesis of Covalent Organic Multicycles

Covalent organic multicycles (COMs) have been designed and synthesized via the covalent assembly of rigid three-arm Y-shaped and U-shaped building blocks. These COMs have a precise tricyclic structure and exhibit remarkable solubility in a range of common solvents. Featuring well-defined cavities with electron-rich structures, these COMs displayed good adsorption capabilities for iodine in both its vapor and liquid states. Moreover, the solution processability allows for the facile fabrication of these COMs as uniform films on different substrates via the spin coating methods.

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来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.