离子交换树脂去除水溶液中含氟聚烯烃的研究

Q3 Materials Science
Wan Nursyafiqah Wan Zamri, Keat Khim Ong, Norherdawati Kasim, Syed Mohd Shafiq Syed Ahmad, Nor Laili-Azua Jamari
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引用次数: 0

摘要

氟调聚物(FT)是一类全氟烷基物质(PFAS),由于其独特的化学性质而具有多种用途。然而,氟调聚物及其一些分解产物由于其持久性、生物蓄积性和潜在毒性而引起了环境和健康问题。因此,从工业废料中去除它是必要的。本研究研究了阴离子交换树脂作为吸附剂对氟端聚烯烃(FTO)的去除。研究了三种不同的参数:吸附剂用量、接触时间和FTO初始浓度。其他化合物对去除FTO的影响也进行了研究。利用扫描电子显微镜(SEM)和布鲁诺尔-埃米特-泰勒(BET)分别对阴离子交换树脂的表面形貌和表面积进行了表征。阴离子交换体表面呈光滑断裂结构,表面积为2.0381 mg2 g−1。结果表明,在最佳吸附条件(1.25 mg, 5 h, 400 mg L−1)下,FTO的去除率高达80%。此外,FTO的去除效率不受其他干扰化合物的影响。这项工作提供的通过阴离子交换树脂去除FTO的理解将导致更有效地应用于从环境中去除氟调聚物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Removal of Fluorotelomer Olefin from Aqueous Solution by Ion Exchange Resin

Removal of Fluorotelomer Olefin from Aqueous Solution by Ion Exchange Resin

Fluorotelomers (FT) are a class of perfluoroalkyl substances (PFAS) that have a variety of applications due to their unique chemical properties. However, fluorotelomers and some of their breakdown products have raised environmental and health concerns due to their persistence, bioaccumulation, and potential toxicity. Hence, its removal from industrial waste is essential. In this study, anion exchange resin as an adsorbent is investigated for fluorotelomer olefin (FTO) removal. Three different parameters are investigated: adsorbent dosage, contact time, and initial concentration of FTO. The effects of other compounds on FTO removal are also investigated. The surface morphology and surface area of anion exchange resin are also conducted using a scanning electron microscope (SEM) and Brunauer–Emmett–Teller (BET), respectively. The surface of anion exchange shows smooth and fractured structure with 2.0381 mg2 g−1 surface area. The results show fast and high removal of FTO up to 80% using optimum sorption condition (1.25 mg, 5 h, and 400 mg L−1). In addition, the removal efficiency of FTO is not affected by the presence of other interference compounds. The understanding of FTO removal through anion exchange resin offered by this work should lead to more effective applications for fluorotelomers removal from the environment.

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来源期刊
Macromolecular Symposia
Macromolecular Symposia Materials Science-Polymers and Plastics
CiteScore
1.50
自引率
0.00%
发文量
226
期刊介绍: Macromolecular Symposia presents state-of-the-art research articles in the field of macromolecular chemistry and physics. All submitted contributions are peer-reviewed to ensure a high quality of published manuscripts. Accepted articles will be typeset and published as a hardcover edition together with online publication at Wiley InterScience, thereby guaranteeing an immediate international dissemination.
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