{"title":"松潘-甘孜造山带东南部江朗丘晚新元古代和丰富的变质火山-沉积层序有利于铜的表生成矿作用","authors":"Yanpei Dai , Yudi Zhu , Shengxian Liang , Qing Zhou","doi":"10.1016/j.lithos.2025.107996","DOIUrl":null,"url":null,"abstract":"<div><div>The Jianglang Dome in the southeastern Songpan-Ganze Orogen, contains a metavolcano-sedimentary sequence (Liwu Group) which hosts high-grade stratiform Cu deposits. Here we report geochemical, chronological and isotopic data of the Liwu Group, to explore the petrogenetic model, metal fertility and basement nature. This sequence is composed of metasedimentary and intercalated metabasic rocks, which contain detrital zircons and xenocrysts with U-Pb ages of 2812–540 Ma (<em>n</em> = 159). Among them, several zircons yield three discordia curves with lower intercepts of 547 Ma (<em>n</em> = 8), 543 Ma (<em>n</em> = 19) and 548 Ma (<em>n</em> = 16). Besides, the youngest concordant zircons show magmatic affinity, and have a weighted mean age of 544.5 Ma (<em>n</em> = 11). These age data are coeval with ca. 545 Ma arc magmatism in the Northern Gondwana, and we assign a Late Neoproterozoic age of ca. 544.5–538.8 Ma for the Liwu Group protoliths. This result, according to a chalcopyrite Re-Os isochron age of 549 ± 11 Ma (<em>n</em> = 5), indicates syngenetic mineralization. The metabasic rocks show depletion in HFSE, MORB-like REE patterns, whole-rock positive ε<sub>Nd</sub>(t) values of +11.3 to +6.2, and varying zircon ε<sub>Hf</sub>(t) values of +12.8 to −17.9. These rocks were thus derived from high-degree melting of spinel lherzolite, and suffered slightly crustal contamination. The metasedimentary rocks have moderate weathering (CIA = 82.8–54.4), moderate maturity (ICV = 1.05–0.72), whole-rock negative ε<sub>Nd</sub>(t) values of −9.0 to −9.8, and wide zircon ε<sub>Hf</sub>(t) values of +12.0 to −20.3; they were fed from adjacent continental blocks and volcanic arc. Our integrated data suggest that the Liwu Group protoliths were formed in an incipient back-arc basin along the Gondwana margin. Metabasic and metasedimentary rocks in this basin, were fertile in metal elements (e.g., Cu and Co) and thus facilitated epigenetic mineralization. Combined with regional comparison, our results indicate further mineralization potential in the analogous domes of the Songpan-Ganze Orogen.</div></div>","PeriodicalId":18070,"journal":{"name":"Lithos","volume":"500 ","pages":"Article 107996"},"PeriodicalIF":2.9000,"publicationDate":"2025-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Late Neoproterozoic and fertile metavolcano-sedimentary sequence facilitated epigenetic Cu mineralization in the Jianglang Dome, southeastern Songpan-Ganze Orogen\",\"authors\":\"Yanpei Dai , Yudi Zhu , Shengxian Liang , Qing Zhou\",\"doi\":\"10.1016/j.lithos.2025.107996\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The Jianglang Dome in the southeastern Songpan-Ganze Orogen, contains a metavolcano-sedimentary sequence (Liwu Group) which hosts high-grade stratiform Cu deposits. Here we report geochemical, chronological and isotopic data of the Liwu Group, to explore the petrogenetic model, metal fertility and basement nature. This sequence is composed of metasedimentary and intercalated metabasic rocks, which contain detrital zircons and xenocrysts with U-Pb ages of 2812–540 Ma (<em>n</em> = 159). Among them, several zircons yield three discordia curves with lower intercepts of 547 Ma (<em>n</em> = 8), 543 Ma (<em>n</em> = 19) and 548 Ma (<em>n</em> = 16). Besides, the youngest concordant zircons show magmatic affinity, and have a weighted mean age of 544.5 Ma (<em>n</em> = 11). These age data are coeval with ca. 545 Ma arc magmatism in the Northern Gondwana, and we assign a Late Neoproterozoic age of ca. 544.5–538.8 Ma for the Liwu Group protoliths. This result, according to a chalcopyrite Re-Os isochron age of 549 ± 11 Ma (<em>n</em> = 5), indicates syngenetic mineralization. The metabasic rocks show depletion in HFSE, MORB-like REE patterns, whole-rock positive ε<sub>Nd</sub>(t) values of +11.3 to +6.2, and varying zircon ε<sub>Hf</sub>(t) values of +12.8 to −17.9. These rocks were thus derived from high-degree melting of spinel lherzolite, and suffered slightly crustal contamination. The metasedimentary rocks have moderate weathering (CIA = 82.8–54.4), moderate maturity (ICV = 1.05–0.72), whole-rock negative ε<sub>Nd</sub>(t) values of −9.0 to −9.8, and wide zircon ε<sub>Hf</sub>(t) values of +12.0 to −20.3; they were fed from adjacent continental blocks and volcanic arc. Our integrated data suggest that the Liwu Group protoliths were formed in an incipient back-arc basin along the Gondwana margin. Metabasic and metasedimentary rocks in this basin, were fertile in metal elements (e.g., Cu and Co) and thus facilitated epigenetic mineralization. Combined with regional comparison, our results indicate further mineralization potential in the analogous domes of the Songpan-Ganze Orogen.</div></div>\",\"PeriodicalId\":18070,\"journal\":{\"name\":\"Lithos\",\"volume\":\"500 \",\"pages\":\"Article 107996\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2025-02-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Lithos\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0024493725000556\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Lithos","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0024493725000556","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0
摘要
松潘-甘孜造山带东南部的江朗丘发育一变质火山-沉积层序(理武群),具有高品位层状铜矿床。本文报道了李武群的地球化学、年代学和同位素资料,探讨了岩石成因模式、金属富性和基底性质。该层序由变质沉积岩和夹层变质岩组成,含碎屑锆石和杂晶,U-Pb年龄为2812 ~ 540 Ma (n = 159)。其中,部分锆石形成了3条不均匀曲线,下截距分别为547 Ma (n = 8)、543 Ma (n = 19)和548 Ma (n = 16)。最年轻的协和锆石具有岩浆亲和性,加权平均年龄为544.5 Ma (n = 11)。这些年龄资料与冈瓦纳北部约545 Ma的弧岩浆活动时间一致,推测力坞群原岩的年龄为约544.5 ~ 538.8 Ma。黄铜矿Re-Os等时年龄为549±11 Ma (n = 5),显示同生成矿作用。变质基性岩石表现为HFSE衰竭,类morb型REE模式,全岩正εNd(t)值为+11.3 ~ +6.2,锆石εHf(t)值为+12.8 ~−17.9。因此,这些岩石来自尖晶石和辉橄榄石的高度熔融,并受到轻微的地壳污染。变质沉积岩风化强度中等(CIA = 82.8 ~ 54.4),成熟度中等(ICV = 1.05 ~ 0.72),全岩负εNd(t)值为−9.0 ~−9.8,宽锆石εHf(t)值为+12.0 ~−20.3;它们来自邻近的大陆块体和火山弧。综合资料表明,黎武群原岩形成于冈瓦纳盆地边缘的弧后盆地。该盆地的变质基性和变质沉积岩富含铜、钴等金属元素,有利于后成成矿作用。结合区域对比,进一步指出了松潘-甘孜造山带类似穹窿的成矿潜力。
Late Neoproterozoic and fertile metavolcano-sedimentary sequence facilitated epigenetic Cu mineralization in the Jianglang Dome, southeastern Songpan-Ganze Orogen
The Jianglang Dome in the southeastern Songpan-Ganze Orogen, contains a metavolcano-sedimentary sequence (Liwu Group) which hosts high-grade stratiform Cu deposits. Here we report geochemical, chronological and isotopic data of the Liwu Group, to explore the petrogenetic model, metal fertility and basement nature. This sequence is composed of metasedimentary and intercalated metabasic rocks, which contain detrital zircons and xenocrysts with U-Pb ages of 2812–540 Ma (n = 159). Among them, several zircons yield three discordia curves with lower intercepts of 547 Ma (n = 8), 543 Ma (n = 19) and 548 Ma (n = 16). Besides, the youngest concordant zircons show magmatic affinity, and have a weighted mean age of 544.5 Ma (n = 11). These age data are coeval with ca. 545 Ma arc magmatism in the Northern Gondwana, and we assign a Late Neoproterozoic age of ca. 544.5–538.8 Ma for the Liwu Group protoliths. This result, according to a chalcopyrite Re-Os isochron age of 549 ± 11 Ma (n = 5), indicates syngenetic mineralization. The metabasic rocks show depletion in HFSE, MORB-like REE patterns, whole-rock positive εNd(t) values of +11.3 to +6.2, and varying zircon εHf(t) values of +12.8 to −17.9. These rocks were thus derived from high-degree melting of spinel lherzolite, and suffered slightly crustal contamination. The metasedimentary rocks have moderate weathering (CIA = 82.8–54.4), moderate maturity (ICV = 1.05–0.72), whole-rock negative εNd(t) values of −9.0 to −9.8, and wide zircon εHf(t) values of +12.0 to −20.3; they were fed from adjacent continental blocks and volcanic arc. Our integrated data suggest that the Liwu Group protoliths were formed in an incipient back-arc basin along the Gondwana margin. Metabasic and metasedimentary rocks in this basin, were fertile in metal elements (e.g., Cu and Co) and thus facilitated epigenetic mineralization. Combined with regional comparison, our results indicate further mineralization potential in the analogous domes of the Songpan-Ganze Orogen.
期刊介绍:
Lithos publishes original research papers on the petrology, geochemistry and petrogenesis of igneous and metamorphic rocks. Papers on mineralogy/mineral physics related to petrology and petrogenetic problems are also welcomed.