IF 3.3 3区 化学 Q2 CHEMISTRY, PHYSICAL
James M. F. Morris, Jarred Potter, Demetris Bates, Chuanli Wu, Craig M. Robertson, Simon J. Higgins, Richard J. Nichols, Paul J. Low, Andrea Vezzoli
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引用次数: 0

摘要

过去 9 年来,闪烁噪声分析在分子电子学领域得到了广泛应用。结的噪声功率及其缩放指数 n 的值提供了单分子结中散射态空间重叠的信息,为了解单分子水平的量子输运现象提供了独特的见解。这种分析工具的主要缺点是采用的方法不一致,导致在不同条件下或不同实验室获得的数据集不可复制。在此,我们提供了一条通往可重复性更高的方法论的途径,详细说明了目前采用的公认相关技术存在的问题,并介绍了使用统计学上更稳健的数据处理标准和更低的数据采集参数阈值的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Digging through the (Statistical) Dirt: A Reproducible Method for Single-Molecule Flicker Noise Analysis

Digging through the (Statistical) Dirt: A Reproducible Method for Single-Molecule Flicker Noise Analysis
Flicker noise analysis has found widespread use in the molecular electronics community over the past 9 years. The noise power of the junctions and the value of its scaling exponent n provide information on the spatial overlap of scattering states in single-molecule junctions and give unique insights into quantum transport phenomena at the single-molecule level. The predominant drawback of this analytical tool is the inconsistency of the methodologies employed, resulting in irreproducibility across data sets acquired in different conditions or in different laboratories. Herein, we provide a pathway to a more reproducible methodology, detailing issues with the currently accepted correlation techniques employed and introducing the use of more statistically robust data processing criteria and lower thresholds for data acquisition parameters.
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来源期刊
The Journal of Physical Chemistry C
The Journal of Physical Chemistry C 化学-材料科学:综合
CiteScore
6.50
自引率
8.10%
发文量
2047
审稿时长
1.8 months
期刊介绍: The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.
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