基于环氧磷苯树脂的环氧粘结剂改性剂

IF 0.7 4区 化学 Q4 CHEMISTRY, PHYSICAL
S. S. Malakhovskii, I. V. Tarasov, N. V. Kostromina, Yu. V. Olikhova, I. Yu. Gorbunova
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引用次数: 0

摘要

研究了使用环氧磷苯树脂作为用 4,4-二氨基二苯甲烷固化的环氧二乙烷基体的改性剂的可能性。动态机械分析表明,在环氧二乙烯树脂中引入改性剂后,橡胶弹性模量和玻璃化转变温度相对于未改性基体都有所提高。根据橡胶弹性模量计算出的交联分子质量在环氧二乙烯基体中引入环氧磷苯树脂后有所降低,这表明改性体系中的交联密度有所增加。随着粘合剂中环氧膦嗪树脂含量的增加,复合材料的冲击粘度比未改性基体的冲击粘度增加。这种体系中的三维网络结构碎片可以成为冲击能量消散器。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Epoxy Binder Modifier Based on Epoxyphosphazene Resin

Epoxy Binder Modifier Based on Epoxyphosphazene Resin

The possibility of using epoxyphosphazene resin as a modifier for the epoxydiane matrix cured with 4,4-diaminodiphenylmethane has been studied. A dynamic mechanical analysis showed that with a modifier introduced in epoxydiane resin, the rubber elasticity modulus and the glass transition temperature increase relative to those of the unmodified matrix. The molecular mass between the crosslinks, calculated from the rubber elasticity modulus, decreases when epoxyphosphazene resin is introduced in the epoxydiane matrix, indicating an increase in the density of crosslinking in the modified systems. With an increase in the content of epoxyphosphazene resin in the binder, the impact viscosity of the composites increases compared to that of the unmodified matrix. The fragments of the three-dimensional network structure in such systems can be impact energy dissipators.

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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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