{"title":"5,7-二(4-甲氧基苯基)-1,2,3,4,4a,5-六氢- 13h -苯并咪唑喹啉的合成与氧化转化","authors":"L. N. Harchenko, K. V. Maslov, O. Yu. Slabko","doi":"10.1134/S1070428024120078","DOIUrl":null,"url":null,"abstract":"<p>The reaction of 4,4′-dimethoxychalcone with cyclohexanone gave 1,5-diketone which was condensed with <i>o</i>-phenylenediamine to produce 5,7-bis(4-methoxyphenyl)-1,2,3,4,4a,5-hexahydro-13<i>H</i>-benzimidazo[2,1-<i>j</i>]quinoline. The oxidation and oxidative coupling of the latter with some primary amines and benzoylacetonitrile afforded fused heterocyclic <i>p</i>-quinoid compounds.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"60 12","pages":"2356 - 2361"},"PeriodicalIF":0.9000,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Oxidative Transformations of 5,7-Bis(4-methoxyphenyl)-1,2,3,4,4a,5-hexahydro-13H-benzimidazo[2,1-j]quinoline\",\"authors\":\"L. N. Harchenko, K. V. Maslov, O. Yu. Slabko\",\"doi\":\"10.1134/S1070428024120078\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reaction of 4,4′-dimethoxychalcone with cyclohexanone gave 1,5-diketone which was condensed with <i>o</i>-phenylenediamine to produce 5,7-bis(4-methoxyphenyl)-1,2,3,4,4a,5-hexahydro-13<i>H</i>-benzimidazo[2,1-<i>j</i>]quinoline. The oxidation and oxidative coupling of the latter with some primary amines and benzoylacetonitrile afforded fused heterocyclic <i>p</i>-quinoid compounds.</p>\",\"PeriodicalId\":766,\"journal\":{\"name\":\"Russian Journal of Organic Chemistry\",\"volume\":\"60 12\",\"pages\":\"2356 - 2361\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2025-02-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Organic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070428024120078\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070428024120078","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Synthesis and Oxidative Transformations of 5,7-Bis(4-methoxyphenyl)-1,2,3,4,4a,5-hexahydro-13H-benzimidazo[2,1-j]quinoline
The reaction of 4,4′-dimethoxychalcone with cyclohexanone gave 1,5-diketone which was condensed with o-phenylenediamine to produce 5,7-bis(4-methoxyphenyl)-1,2,3,4,4a,5-hexahydro-13H-benzimidazo[2,1-j]quinoline. The oxidation and oxidative coupling of the latter with some primary amines and benzoylacetonitrile afforded fused heterocyclic p-quinoid compounds.
期刊介绍:
Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.