[FeCl3·6H2O-TsOH·H2O]催化降冰片烯与有机腈反应的微波活化研究

IF 0.9 4区化学 Q4 CHEMISTRY, ORGANIC

Russian Journal of Organic Chemistry Pub Date : 2025-02-06 DOI:10.1134/S107042802412008X

K. S. Frolova, T. P. Zosim, I. R. Ramazanov

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引用次数: 0

摘要

提出了一种由20 mol % FeCl3·6H2O和20 mol %对甲苯磺酸组成的高效催化体系，在95℃微波照射下，用有机腈在甲苯中酰胺化降冰片烯，得到了相应的N-（降冰片烯-2-外氧基）羧酰胺，收率高。本文首次证实了cl3在芳基氰化物修饰降冰片烯中的效率。

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Microwave Activation of the [FeCl3·6H2O–TsOH·H2O]-Catalyzed Reaction of Norbornene with Organic Nitriles

An efficient catalytic system consisting of 20 mol % FeCl₃·6H₂O and 20 mol % of p-toluenesulfonic acid has been proposed for the amidation of norbornene in toluene with organic nitriles under microwave irradiation at 95°C for 1 h. The corresponding N-(norbornan-2-exo-yl) carboxamides have been obtained with high yields. The efficiency of InCl₃ in the amidation of norbornene with aryl cyanides has been demonstrated for the first time.

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来源期刊

Russian Journal of Organic Chemistry 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

139

审稿时长

3-6 weeks

期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.