Cp2ZrCl2 与三乙基铝催化的氨甲基烯丙基 2-氨乙基氨化反应

IF 0.8 4区化学 Q4 CHEMISTRY, ORGANIC

Russian Journal of Organic Chemistry Pub Date : 2025-02-06 DOI:10.1134/S1070428024120261

T. P. Zosim, R. N. Kadikova, I. R. Ramazanov

引用次数: 0

摘要

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cp2ZrCl2-Catalyzed 2-Aluminoethylalumination of Aminomethyl Allenes with Triethylaluminum

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Cp2ZrCl2-Catalyzed 2-Aluminoethylalumination of Aminomethyl Allenes with Triethylaluminum

It was shown for the first time that the Cp₂ZrCl₂-catalyzed reaction of dialkylaminomethyl allenes (N,N-dialkylbuta-2,3-dien-1-amines) with triethylaluminum results in regio- and stereoselective formation of (Z)-N,N-dialkylhex-2-en-1-amines. A probable reaction mechanism has been proposed.

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来源期刊

Russian Journal of Organic Chemistry 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

139

审稿时长

3-6 weeks

期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.