氧化还原液流电池中电解质输运特性的研究进展

Xiangchi Liu , Lyuming Pan , Haoyao Rao , Yilin Wang
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引用次数: 0

摘要

氧化还原液流电池是一种极具竞争力的电网级储能技术,尤其适用于大规模、长时间的储能。在氧化还原液流电池中,能量以电化学方式存储在电解液中,在泵的驱动下,电解液在储液池和电极之间循环。因此,电解液是氧化还原液流电池的重要组成部分之一,其理化性质在很大程度上决定了电池的性能。本文综述了氧化还原液流电池中各类电解质的输运特性,包括粘度、扩散系数和电导率。本文概述了这些基本输运特性的测量方法和原理,提供了不同类型电解质的粘度、扩散系数和电导率的典型值,并研究了这些特性对氧化还原液流电池的质量和电荷输运以及电池整体性能的影响。为更好地理解和优化氧化还原液流电池,提出了有见地的观点,以桥接电解质传输特性与技术相关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A review of transport properties of electrolytes in redox flow batteries
Redox flow battery is a competitive grid-level energy storage technique that is especially suitable for large-scale and long-duration energy storage. In redox flow batteries, the energy is stored in the electrolyte electrochemically, which circulates between the reservoir and the electrode, driven by the pump. Therefore, the electrolyte is one of the most important components in redox flow batteries and its physicochemical properties greatly determine the battery performance. Here, the transport properties of various types of electrolytes in redox flow batteries are reviewed, including viscosity, diffusion coefficient, and conductivity. This paper outlines the measuring methods and principles for these fundamental transport properties, provides typical values of viscosity, diffusion coefficient, and conductivity for different types of electrolytes, and examines the impact of those properties on the mass and charge transport as well as the overall battery performance in redox flow batteries. Insightful perspectives are proposed to bridge the electrolyte transport properties to technological relevance for better understanding and optimizing redox flow batteries.
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