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AlPCl8的晶体结构

IF 0.5 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2024-11-01 DOI:10.1107/S2056989024010661

Hyeonjin Seo , Seungyong Shin , Seung-Tae Hong

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引用次数: 0

摘要

利用单晶x射线衍射数据对氯化磷铝的晶体结构进行了测定和细化。该化合物在邻菱方基Pbcm中结晶，其不对称单元由1个Al原子、1个P原子和5个Cl原子组成。其结构为分离的AlCl4和PCl4四面体，与FePCl8和GaPCl8同构。利用单晶x射线衍射数据测定并细化了氯化磷铝（学名：磷酸四氯四氯）、（PCl4）[AlCl4]或AlPCl8的晶体结构。该化合物在邻菱形空间群Pbcm中结晶。不对称单元由一个Al原子、一个P原子和五个Cl原子组成。其结构为分离的AlCl4和PCl4四面体，与FePCl8和GaPCl8同构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Crystal structure of AlPCl8

The crystal structure of aluminium phosphorus chloride was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm with the asymmetric unit comprises one Al atom, one P atom, and five Cl atoms. The structure is characterized by isolated AlCl₄ and PCl₄ tetrahedra, isostructural with FePCl₈ and GaPCl₈.

The crystal structure of aluminium phosphorus chloride (systematic name: phosphorus tetrachloride tetrachloridoaluminate), (PCl₄)[AlCl₄] or AlPCl₈, was determined and refined using single-crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Pbcm. The asymmetric unit comprises one Al atom, one P atom, and five Cl atoms. The structure is characterized by isolated AlCl₄ and PCl₄ tetrahedra, isostructural with FePCl₈ and GaPCl₈.

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.

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