A. Lushchik, A. Podelinska, V. Seeman, E. Shablonin, E. A. Kotomin* and V. N. Kuzovkov,
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Open Questions on the Thermal Stability of Primary Electronic Centers in Irradiated MgO Single Crystals
Basic properties of the simplest radiation defect, the F+ center (an oxygen vacancy with a trapped electron), in the simplest oxide material (MgO with a cubic lattice structure) remain for a long time a subject of discussion, in light of highly contradictory literature data. In this paper, new data on the electron paramagnetic resonance (EPR) and optical absorption measurements for the neutron- and energetic-ion-irradiated (70 MeV Ar) MgO single crystals are discussed. Theoretical analysis of the diffusion-controlled F+ center isochronal annealing is performed; the obtained migration energies for oxygen interstitials are discussed in light of the available calculations on the mobility of both neutral and charged oxygen interstitials in metal oxides.
期刊介绍:
The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.