基于n -苯基吩噻嗪的超交联聚合物可回收，有机转化的非均相光催化：获取6-二氟甲基菲菲啶的策略

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-01-23 DOI:10.1021/acs.orglett.4c04585

Shengjie Song, Wenjian Wang, Yali He, Xiaoye Cheng, Zhi Chen, Jiadi Zhou, Jianjun Li

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引用次数: 0

摘要

本文设计并构建了一种基于n -苯基吩噻嗪的超交联聚合物（PTH-HCP），作为有机转化的无金属非均相光催化剂。表征实验表明，该聚合物具有优异的稳定性、广泛的表面积和优异的光电响应特性。此外，PTH-HCP在光化学驱动的二氟甲基化/环化反应中表现出良好的催化效率和可回收性。本研究为聚合物光催化剂的设计和构建提供了思路，并为其在合成领域的广阔应用前景提供了支持。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

N-Phenylphenothiazine-based Hyper-cross-linked Polymers for Recyclable, Heterogeneous Photocatalysis of Organic Transformations: A Strategy to Access 6-Difluoromethyl-phenanthridines

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N-Phenylphenothiazine-based Hyper-cross-linked Polymers for Recyclable, Heterogeneous Photocatalysis of Organic Transformations: A Strategy to Access 6-Difluoromethyl-phenanthridines

Herein, a N-phenylphenothiazine-based hyper-cross-linked polymer (PTH-HCP) was finely designed and constructed, which serves as a metal-free heterogeneous photocatalyst for organic transformations. Characterization experiments have shown that this polymer demonstrates outstanding stability, extensive surface area, and exceptional photoelectric response properties. Moreover, PTH-HCP showed good catalytic efficiency and recyclability in the photochemically driven difluoromethylation/cyclization reactions. This work provides a strategy for the design and construction of polymer photocatalysts and offers support for their broad prospects in synthetic applications.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.