{"title":"低渗致密多孔介质中界面现象对凝析气相行为的影响","authors":"Hanmin Tu, Shiyong Hu, Ping Guo, Xinyu Wang, Zhongshun Min, Haiyan He","doi":"10.1134/S0036024424702261","DOIUrl":null,"url":null,"abstract":"<p>Low-permeability and tight condensate gas reservoirs are critically important in gas field development due to their substantial reserves and high economic value. However, retrograde condensation significantly affects oil and gas productivity during development. Understanding the impacts of interfacial phenomena in porous media is crucial for enhancing recovery rates of gas and condensate oil. This study integrates the capillary effect and adsorption into a phase equilibrium model, based on the Peng–Robinson equation of state (PR-EOS), to account for interfacial phenomena. The results indicate that the interfacial phenomena significantly impact the phase behavior of condensate gas. Interfacial effects increased the dew point pressure (<i>P</i><sub><i>d</i></sub>) by 0.47 MPa and the maximum condensate oil saturation (<i>S</i><sub>omax</sub>) by 3.95%. Capillary pressure primarily affects fluid phase behavior and mobility, while adsorption influences fluid composition and interfacial tension. When the capillary radius (<i>r</i>) is less than 100 nm, <i>P</i><sub><i>d</i></sub> increases rapidly with decreasing <i>r</i>. At a pore radius of 30 nm, <i>P</i><sub><i>d</i></sub> and <i>S</i><sub>omax</sub> increased by 1.06 MPa and 5.23%, respectively. Higher heavy component content in the fluids enhances capillary pressure and desorption, leading to increased <i>P</i><sub><i>d</i></sub> and <i>S</i><sub>omax</sub>. Ignoring adsorption and capillary effects can adversely affect reservoir development. The established numerical model considering complex adsorption characteristics and capillary pressure is crucial for understanding phase behavior in high-temperature, high-pressure porous media and optimizing development strategies for condensate gas reservoirs.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"98 13","pages":"2974 - 2990"},"PeriodicalIF":0.7000,"publicationDate":"2025-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Interfacial Phenomena on the Behavior of Condensate Gas Phase in Low-Permeability and Dense Porous Media\",\"authors\":\"Hanmin Tu, Shiyong Hu, Ping Guo, Xinyu Wang, Zhongshun Min, Haiyan He\",\"doi\":\"10.1134/S0036024424702261\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Low-permeability and tight condensate gas reservoirs are critically important in gas field development due to their substantial reserves and high economic value. However, retrograde condensation significantly affects oil and gas productivity during development. Understanding the impacts of interfacial phenomena in porous media is crucial for enhancing recovery rates of gas and condensate oil. This study integrates the capillary effect and adsorption into a phase equilibrium model, based on the Peng–Robinson equation of state (PR-EOS), to account for interfacial phenomena. The results indicate that the interfacial phenomena significantly impact the phase behavior of condensate gas. Interfacial effects increased the dew point pressure (<i>P</i><sub><i>d</i></sub>) by 0.47 MPa and the maximum condensate oil saturation (<i>S</i><sub>omax</sub>) by 3.95%. Capillary pressure primarily affects fluid phase behavior and mobility, while adsorption influences fluid composition and interfacial tension. When the capillary radius (<i>r</i>) is less than 100 nm, <i>P</i><sub><i>d</i></sub> increases rapidly with decreasing <i>r</i>. At a pore radius of 30 nm, <i>P</i><sub><i>d</i></sub> and <i>S</i><sub>omax</sub> increased by 1.06 MPa and 5.23%, respectively. Higher heavy component content in the fluids enhances capillary pressure and desorption, leading to increased <i>P</i><sub><i>d</i></sub> and <i>S</i><sub>omax</sub>. Ignoring adsorption and capillary effects can adversely affect reservoir development. The established numerical model considering complex adsorption characteristics and capillary pressure is crucial for understanding phase behavior in high-temperature, high-pressure porous media and optimizing development strategies for condensate gas reservoirs.</p>\",\"PeriodicalId\":767,\"journal\":{\"name\":\"Russian Journal of Physical Chemistry A\",\"volume\":\"98 13\",\"pages\":\"2974 - 2990\"},\"PeriodicalIF\":0.7000,\"publicationDate\":\"2025-01-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Physical Chemistry A\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0036024424702261\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024424702261","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Influence of Interfacial Phenomena on the Behavior of Condensate Gas Phase in Low-Permeability and Dense Porous Media
Low-permeability and tight condensate gas reservoirs are critically important in gas field development due to their substantial reserves and high economic value. However, retrograde condensation significantly affects oil and gas productivity during development. Understanding the impacts of interfacial phenomena in porous media is crucial for enhancing recovery rates of gas and condensate oil. This study integrates the capillary effect and adsorption into a phase equilibrium model, based on the Peng–Robinson equation of state (PR-EOS), to account for interfacial phenomena. The results indicate that the interfacial phenomena significantly impact the phase behavior of condensate gas. Interfacial effects increased the dew point pressure (Pd) by 0.47 MPa and the maximum condensate oil saturation (Somax) by 3.95%. Capillary pressure primarily affects fluid phase behavior and mobility, while adsorption influences fluid composition and interfacial tension. When the capillary radius (r) is less than 100 nm, Pd increases rapidly with decreasing r. At a pore radius of 30 nm, Pd and Somax increased by 1.06 MPa and 5.23%, respectively. Higher heavy component content in the fluids enhances capillary pressure and desorption, leading to increased Pd and Somax. Ignoring adsorption and capillary effects can adversely affect reservoir development. The established numerical model considering complex adsorption characteristics and capillary pressure is crucial for understanding phase behavior in high-temperature, high-pressure porous media and optimizing development strategies for condensate gas reservoirs.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.