From 0D to 2D: Microwave-assisted Synthesis of Electrically Conductive Metal-Organic Frameworks with Controlled Morphologies

Morphology control of electrically conductive metal-organic frameworks (EC-MOFs) can be a powerful means to tune their surface area and carrier transport pathways, particularly beneficial for energy conversion and storage. However, controlling EC-MOFs’ morphology is underexplored due to the uncontrollable crystal nucleation and rapid growth kinetics. This work introduces a microwave-assisted strategy to readily synthesize Cu-HHTP (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene) with controlled morphologies. We employed modulators to facilitate particles’ directional growth to 1D and 2D crystals. Meanwhile, we found that ultrasonication can manipulate crystal seeding, yielding 0D spherical Cu-HHTP crystals. Electronic conductivity measurements suggest that the isotropic nature of the 0D crystals allows a conductivity of 7.34 × 10^-1 S cm^-1, much higher than 1D and 2D counterparts’. Additionally, the controlled 0D morphology enhanced the material’s capacitance and effective surface area and significantly improved its photocurrent response. These findings underscore the pivotal impact of controlled morphology in optimizing EC-MOFs’ physicochemical properties.