化学反应和传输中的能量景观。

IF 2.3 3区 化学 Q3 CHEMISTRY, PHYSICAL
Karl-Michael Weitzel
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引用次数: 0

摘要

分子化学反应和原子在固体介质中的传输都是由能量格局决定的,在这种格局中,表面上不同的过程发生了。化学反应可以被描述为两个化学实体在一个共同的势能表面上的协同易位。固体中原子的输运可以设想为单个粒子在构成固体的所有其他粒子的势能格局中的易位。这份手稿的目的是证明共同点,但也明显的差异在物理化学过程,他们的实验量化和理论建模。这项工作将涵盖从历史基础一直到当前挑战的范围。20世纪初,科学家们在这两个领域都很活跃。Wilhelm Jost是德国固体输运和反应动力学领域的先驱,在过去的50年里,这两个领域一直处于分离状态。现在是时候把这些领域重新结合在一起了。最后,这表明在转运领域获得的知识实际上可能会刺激分子反应性领域的进步,反之亦然。在这里,能源格局对于以知识为基础的进步至关重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Energy Landscapes in Chemical Reactions and Transport.

Both, molecular chemical reactions and transport of atoms in solid media are determined by the energy landscape in which the seemingly different processes take place. Chemical reactions can be described as cooperative translocation of two chemical entities on a common potential energy surface. Transport of atoms in a solid can be envisaged as the translocation of a single particle in the potential energy landscape of all other particles constituting the solid. The goal of this manuscript is to demonstrate common grounds but also distinct differences in the physico-chemical processes, their experimental quantification and their theoretical modelling. This work will span the range from the historical foundations all the way to the current challenges. While scientists at the beginning of the 20th century where commonly active in both fields, e. g., Wilhelm Jost has pioneered and shaped the field of transport in solids and reaction kinetics in Germany, the fields have drifted apart for the last 50 decades. It is now time to bring the fields together again. Ultimately, it is suggested that knowledge gained in the field of transport may in fact stimulate advancement in the field of molecular reactivity and vice versa. Here, the energy landscapes are pivotal for knowledge-based advancement.

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来源期刊
Chemphyschem
Chemphyschem 化学-物理:原子、分子和化学物理
CiteScore
4.60
自引率
3.40%
发文量
425
审稿时长
1.1 months
期刊介绍: ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.
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