Ferhan Slamang , Eric Cyriel Hosten , Richard Betz
{"title":"3-Iodo-aniline。","authors":"Ferhan Slamang , Eric Cyriel Hosten , Richard Betz","doi":"10.1107/S2414314624012264","DOIUrl":null,"url":null,"abstract":"<div><div>The asymmetric unit of the title compound, the <em>meta</em>-iodinated derivative of aniline, contains two complete molecules. In the crystal, cooperative hydrogen bonds of the N–H⋯N type connect the molecules into infinite chains along the <em>a-</em>axis direction. Dispersive I⋯I contacts extend these chains to sheets perpendicular to the crystallographic <em>c</em> axis.</div></div><div><div>The title compound, C<sub>6</sub>H<sub>6</sub>IN, is the <em>meta</em>-iodinated derivative of aniline. The asymmetric unit contains two molecules. The structure was refined as a two-component inversion twin with a volume ratio of 55.6:44.4. In the crystal, cooperative hydrogen bonds of the N–H⋯N type connect the molecules into infinite chains propagating along the <em>a-</em>axis direction. Dispersive I⋯I contacts extend these chains to sheets perpendicular to the crystallographic <em>c</em> axis.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (161KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 12","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11701754/pdf/","citationCount":"0","resultStr":"{\"title\":\"3-Iodoaniline\",\"authors\":\"Ferhan Slamang , Eric Cyriel Hosten , Richard Betz\",\"doi\":\"10.1107/S2414314624012264\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The asymmetric unit of the title compound, the <em>meta</em>-iodinated derivative of aniline, contains two complete molecules. In the crystal, cooperative hydrogen bonds of the N–H⋯N type connect the molecules into infinite chains along the <em>a-</em>axis direction. Dispersive I⋯I contacts extend these chains to sheets perpendicular to the crystallographic <em>c</em> axis.</div></div><div><div>The title compound, C<sub>6</sub>H<sub>6</sub>IN, is the <em>meta</em>-iodinated derivative of aniline. The asymmetric unit contains two molecules. The structure was refined as a two-component inversion twin with a volume ratio of 55.6:44.4. In the crystal, cooperative hydrogen bonds of the N–H⋯N type connect the molecules into infinite chains propagating along the <em>a-</em>axis direction. Dispersive I⋯I contacts extend these chains to sheets perpendicular to the crystallographic <em>c</em> axis.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (161KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 12\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11701754/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624001214\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624001214","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The asymmetric unit of the title compound, the meta-iodinated derivative of aniline, contains two complete molecules. In the crystal, cooperative hydrogen bonds of the N–H⋯N type connect the molecules into infinite chains along the a-axis direction. Dispersive I⋯I contacts extend these chains to sheets perpendicular to the crystallographic c axis.
The title compound, C6H6IN, is the meta-iodinated derivative of aniline. The asymmetric unit contains two molecules. The structure was refined as a two-component inversion twin with a volume ratio of 55.6:44.4. In the crystal, cooperative hydrogen bonds of the N–H⋯N type connect the molecules into infinite chains propagating along the a-axis direction. Dispersive I⋯I contacts extend these chains to sheets perpendicular to the crystallographic c axis.