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Rh（III）催化Csp2-H活化引发吲哚的2,3-二胺化反应

Organic chemistry frontiers : an international journal of organic chemistry Pub Date : 2025-01-22 DOI:10.1039/d4qo02017k
Chengjie Wang , Huanfeng Jiang , Wei Zeng
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引用次数: 0

摘要

研究了Rh（III）催化吲哚与n -烷氧基酰胺的2,3-二胺化反应。该方法提供了一种获得2-（n -酰基氨基）-3-氨基吲哚的高效途径，具有较高的区域选择性。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

Dearomative 2,3-diamination of indoles triggered by Rh(iii)-catalyzed Csp2–H activation†

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Dearomative 2,3-diamination of indoles triggered by Rh(iii)-catalyzed Csp2–H activation†
An Rh(iii)-catalyzed dearomative 2,3-diamination of indoles with N-alkoxyamides has been developed. The method provides an efficient approach to access 2-(N-acylimino)-3-aminoindolines with high regioselectivity.
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Organic chemistry frontiers : an international journal of organic chemistry
Organic chemistry frontiers : an international journal of organic chemistry
CiteScore
7.80
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