新型钼酸铜氧化硫酸Cu6O2(MoO4)3（SO4）的合成与晶体结构

IF 1.2 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2024-12-27 DOI:10.1134/S0022476624120023

A. S. Borisov, O. I. Siidra, D. O. Charkin, G. V. Nikolaevich, A. S. Baikina, E. V. Nazarchuk, A. Holzheid

{"title":"新型钼酸铜氧化硫酸Cu6O2(MoO4)3（SO4）的合成与晶体结构","authors":"A. S. Borisov, O. I. Siidra, D. O. Charkin, G. V. Nikolaevich, A. S. Baikina, E. V. Nazarchuk, A. Holzheid","doi":"10.1134/S0022476624120023","DOIUrl":null,"url":null,"abstract":"We report synthesis and crystal structure of a new copper molybdate oxosulfate Cu6O2(MoO4)3(SO4). The new compound is obtained in evacuated silica ampoules at 675-725 °C. Cu6O2(MoO4)3(SO4) is monoclinic, space group P21/m, a = 7.5208(4) Å, b = 6.8602(3) Å, c = 14.0019(7) Å, β = 93.471(5)°, V = 721.09(6) Å3, R1 = 0.051. The 3D framework of the new compound consists of oxo-centered [OCu3]4+ chains and MoO4 and SO4 tetrahedra. The structural motif of the new compound is related to the previously described fumarole minerals, glikinite Zn3O(SO4)2 and vergasovaite Cu3O(MoO4)(SO4). The crystal chemical peculiarities of this group of synthetic compounds and minerals are discussed.","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"65 12","pages":"2371 - 2383"},"PeriodicalIF":1.2000,"publicationDate":"2024-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Crystal Structure of Cu6O2(MoO4)3(SO4), New Copper Molybdate Oxosulfate, Structurally Related to Vergasovaite and Glikinite\",\"authors\":\"A. S. Borisov, O. I. Siidra, D. O. Charkin, G. V. Nikolaevich, A. S. Baikina, E. V. Nazarchuk, A. Holzheid\",\"doi\":\"10.1134/S0022476624120023\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"We report synthesis and crystal structure of a new copper molybdate oxosulfate Cu6O2(MoO4)3(SO4). The new compound is obtained in evacuated silica ampoules at 675-725 °C. Cu6O2(MoO4)3(SO4) is monoclinic, space group P21/m, a = 7.5208(4) Å, b = 6.8602(3) Å, c = 14.0019(7) Å, β = 93.471(5)°, V = 721.09(6) Å3, R1 = 0.051. The 3D framework of the new compound consists of oxo-centered [OCu3]4+ chains and MoO4 and SO4 tetrahedra. The structural motif of the new compound is related to the previously described fumarole minerals, glikinite Zn3O(SO4)2 and vergasovaite Cu3O(MoO4)(SO4). The crystal chemical peculiarities of this group of synthetic compounds and minerals are discussed.\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"65 12\",\"pages\":\"2371 - 2383\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2024-12-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476624120023\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624120023","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

报道了一种新型钼酸铜氧硫酸铜Cu6O2(MoO4)3（SO4）的合成及其晶体结构。新化合物在675-725°C的真空二氧化硅安瓿中得到。Cu6O2 (MoO4) 3 (SO4)是单斜,空间群P21 / m = 7.5208 (4) a, b = 6.8602 (3) a, c = 14.0019(7),β= 93.471(5)°,V = 721.09 (6) A3, R1 = 0.051。新化合物的三维骨架由氧中心的[OCu3]4+链和MoO4和SO4四面体组成。新化合物的结构基序与前面描述的富墨孔矿物、闪质岩zn30o (SO4)2和辉长石cu30o (MoO4)（SO4）有关。讨论了这类合成化合物和矿物的晶体化学特性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and Crystal Structure of Cu6O2(MoO4)3(SO4), New Copper Molybdate Oxosulfate, Structurally Related to Vergasovaite and Glikinite

查看原文本刊更多论文

Synthesis and Crystal Structure of Cu6O2(MoO4)3(SO4), New Copper Molybdate Oxosulfate, Structurally Related to Vergasovaite and Glikinite

We report synthesis and crystal structure of a new copper molybdate oxosulfate Cu₆O₂(MoO₄)₃(SO₄). The new compound is obtained in evacuated silica ampoules at 675-725 °C. Cu₆O₂(MoO₄)₃(SO₄) is monoclinic, space group P2₁/m, a = 7.5208(4) Å, b = 6.8602(3) Å, c = 14.0019(7) Å, β = 93.471(5)°, V = 721.09(6) Å³, R₁ = 0.051. The 3D framework of the new compound consists of oxo-centered [OCu₃]⁴⁺ chains and MoO₄ and SO₄ tetrahedra. The structural motif of the new compound is related to the previously described fumarole minerals, glikinite Zn₃O(SO₄)₂ and vergasovaite Cu₃O(MoO₄)(SO₄). The crystal chemical peculiarities of this group of synthetic compounds and minerals are discussed.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.