卤素对3,4,5,6-四氯邻苯二甲酸盐系镧系配位化合物晶体填充的影响

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
CrystEngComm Pub Date : 2024-12-09 DOI:10.1039/D4CE00966E
Fallou Ngom, Chloé Blais, Insa Badiane, Christine Hénaff, Magatte Camara, Carole Daiguebonne and Olivier Guillou
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引用次数: 0

摘要

镧系离子与四氯苯-1,2-二羧酸盐(tcpa2−)之间在水中的晶体生长生成了6种新的配位化合物,它们的化学式分别为[Y(tcpa)(OH)(H2O)3]∞(1)、Nd4(tcpa)6(H2O)22·8H2O(2)、[KLa(tcpa)2(H2O)5·2H2O]∞(3)、[KLa(tcpa)2(H2O)5·2H2O]∞(4)、Y(tcpa)(Htcpa)(H2O)5(5)和[KTb(tcpa)2(H2O)6·H2O]∞(6)]。聚焦于被认为是发光强度关键点的结构特征。由卤素原子的存在引起的趋势被确定。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Influence of halogens on the crystal packing of 3,4,5,6-tetra-chloro-phthalate-based lanthanide coordination compounds†

Influence of halogens on the crystal packing of 3,4,5,6-tetra-chloro-phthalate-based lanthanide coordination compounds†

Crystal growth in water between lanthanide ions and tetra-chloro-benzene-1,2-di-carboxylate (tcpa2−) led to 6 new coordination compounds with respective chemical formulas [Y(tcpa)(OH)(H2O)3] (1), Nd4(tcpa)6(H2O)22·8H2O (2), [KLa(tcpa)2(H2O)10·H2O] (3), [KLa(tcpa)2(H2O)5·2H2O] (4), Y(tcpa)(Htcpa)(H2O)5 (5) and [KTb(tcpa)2(H2O)6·H2O] (6). The crystal structures of these six compounds are described and compared with previously described crystal structures, focusing on the structural characteristics that are known for being key points for luminescence intensity. Trends induced by the presence of halogen atoms are identified.

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来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍: Design and understanding of solid-state and crystalline materials
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