纳米石墨烯的熔融金属合成

IF 15.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2024-12-23 DOI:10.1021/jacs.4c16328

Jacklin H. Smith, Daniel Čavlović, Luke T. Lackovic, Miguel Medina Lopez, Elena Meirzadeh, Michael L. Steigerwald, Xavier Roy, Colin P. Nuckolls, Scott R. Docherty

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引用次数: 0

摘要

本文介绍了一种简单有效的利用液态碱金属对芳烃进行环脱氢的方法。熔融钾与芳烃直接反应，在聚芳烃内部形成六元环和锯齿状结构。该方法扩展到吡啶氮和5元环与芳烃结构的集成以及更大的开壳纳米石墨烯的合成。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Molten Metal Synthesis of Nanographenes

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Molten Metal Synthesis of Nanographenes

This manuscript describes a simple and effective method to cyclodehydrogenate arenes using liquid alkali metals. Direct reaction between molten potassium and arenes forms 6-membered rings and zigzag edged structures within polyarenes. The approach is extended to integration of pyridinic nitrogen and 5-membered rings to arene structures and synthesis of larger, open-shell nanographenes.

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来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.