Mohd Abdul Fatah Abdul Manan , David B. Cordes , Aidan P. McKay
{"title":"甲基2 - [(Z) 5-methyl-2-oxoindolin-3-yl-idene] hydrazinecarbodi-thio-ate。","authors":"Mohd Abdul Fatah Abdul Manan , David B. Cordes , Aidan P. McKay","doi":"10.1107/S2414314624009672","DOIUrl":null,"url":null,"abstract":"<div><div>The crystal structure of a new <em>S</em>-methyl substituted dithiocarbazate imine containing the 5-methylisatin moiety is described.</div></div><div><div>The title dithiocarbazate imine, C<sub>11</sub>H<sub>11</sub>N<sub>3</sub>OS<sub>2</sub>, was obtained from the condensation reaction of <em>S</em>-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a <em>Z</em> configuration about the imine C=N bond, which is associated with an intramolecular N—H⋯O hydrogen bond that closes an <em>S</em>(6) ring. In the crystal, inversion dimers linked by pairwise N—H⋯O hydrogen bonds generate <em>R</em><sup>2</sup><sub>2</sub>(8) loops. The extended structure features C—H⋯S contacts as well as reciprocal carbonyl–carbonyl (C=O⋯C=O) interactions.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (211KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 10","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660172/pdf/","citationCount":"0","resultStr":"{\"title\":\"Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]hydrazinecarbodithioate\",\"authors\":\"Mohd Abdul Fatah Abdul Manan , David B. Cordes , Aidan P. McKay\",\"doi\":\"10.1107/S2414314624009672\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The crystal structure of a new <em>S</em>-methyl substituted dithiocarbazate imine containing the 5-methylisatin moiety is described.</div></div><div><div>The title dithiocarbazate imine, C<sub>11</sub>H<sub>11</sub>N<sub>3</sub>OS<sub>2</sub>, was obtained from the condensation reaction of <em>S</em>-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a <em>Z</em> configuration about the imine C=N bond, which is associated with an intramolecular N—H⋯O hydrogen bond that closes an <em>S</em>(6) ring. In the crystal, inversion dimers linked by pairwise N—H⋯O hydrogen bonds generate <em>R</em><sup>2</sup><sub>2</sub>(8) loops. The extended structure features C—H⋯S contacts as well as reciprocal carbonyl–carbonyl (C=O⋯C=O) interactions.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (211KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 10\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660172/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624001159\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624001159","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The crystal structure of a new S-methyl substituted dithiocarbazate imine containing the 5-methylisatin moiety is described.
The title dithiocarbazate imine, C11H11N3OS2, was obtained from the condensation reaction of S-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a Z configuration about the imine C=N bond, which is associated with an intramolecular N—H⋯O hydrogen bond that closes an S(6) ring. In the crystal, inversion dimers linked by pairwise N—H⋯O hydrogen bonds generate R22(8) loops. The extended structure features C—H⋯S contacts as well as reciprocal carbonyl–carbonyl (C=O⋯C=O) interactions.
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