{"title":"瓜蒌瓜衍生活性炭:高能对称超级电容器的电位电极材料","authors":"Anit Joseph, Arshitha Mathew, Tiju Thomas","doi":"10.1002/cnma.202400112","DOIUrl":null,"url":null,"abstract":"<p>High surface area porous activated carbons obtained from sustainable biomass are excellent functional materials for energy storage applications. This is the first report on snake gourd (Trichosanthes cucumerina) pericarp as a raw material of activated carbon and supercapacitor electrode material. Herein, a simple KOH activation and carbonisation method is used. The obtained SGC900 sample has a surface area of 1841 m<sup>2</sup>/g and an average pore volume of 0.52 cm<sup>3</sup>/g. SGC900 based supercapacitor exhibits good electrochemical storage capacity in 1 M H<sub>2</sub>SO<sub>4</sub> with a specific capacitance of 206 F/g at 1 A/g. The symmetric device delivered an energy density of 11 Wh/kg at a power density of 1.6 kW/kg. It provides a series resistance (R<sub>s</sub>) of 1.2 Ω and a charge transfer resistance R<sub>ct</sub> of 1.9 Ω. Furthermore, the device retains 95 % of capacitance over 5000 cycles. This work presents an easy and feasible approach for producing value-added activated carbon from sustainable biomass, potentially used in high-performance energy storage.</p>","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"10 12","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Trichosanthes Cucumerina Derived Activated Carbon: The Potential Electrode material for High Energy Symmetric Supercapacitor\",\"authors\":\"Anit Joseph, Arshitha Mathew, Tiju Thomas\",\"doi\":\"10.1002/cnma.202400112\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>High surface area porous activated carbons obtained from sustainable biomass are excellent functional materials for energy storage applications. This is the first report on snake gourd (Trichosanthes cucumerina) pericarp as a raw material of activated carbon and supercapacitor electrode material. Herein, a simple KOH activation and carbonisation method is used. The obtained SGC900 sample has a surface area of 1841 m<sup>2</sup>/g and an average pore volume of 0.52 cm<sup>3</sup>/g. SGC900 based supercapacitor exhibits good electrochemical storage capacity in 1 M H<sub>2</sub>SO<sub>4</sub> with a specific capacitance of 206 F/g at 1 A/g. The symmetric device delivered an energy density of 11 Wh/kg at a power density of 1.6 kW/kg. It provides a series resistance (R<sub>s</sub>) of 1.2 Ω and a charge transfer resistance R<sub>ct</sub> of 1.9 Ω. Furthermore, the device retains 95 % of capacitance over 5000 cycles. This work presents an easy and feasible approach for producing value-added activated carbon from sustainable biomass, potentially used in high-performance energy storage.</p>\",\"PeriodicalId\":54339,\"journal\":{\"name\":\"ChemNanoMat\",\"volume\":\"10 12\",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-10-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemNanoMat\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202400112\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemNanoMat","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cnma.202400112","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
从可持续生物质中获得的高表面积多孔活性炭是一种极好的储能功能材料。本文首次报道了以丝瓜果皮为原料制备活性炭和超级电容器电极材料。本文采用一种简单的KOH活化和碳化方法。所得SGC900样品的比表面积为1841 m2/g,平均孔体积为0.52 cm3/g。基于SGC900的超级电容器在1 M H2SO4中表现出良好的电化学存储能力,在1 a /g下的比电容为206 F/g。该对称器件在1.6 kW/kg的功率密度下提供了11 Wh/kg的能量密度。它的串联电阻(Rs)为1.2 Ω,电荷转移电阻Rct为1.9 Ω。此外,该器件在5000次循环中保持95%的电容。这项工作提出了一种简单可行的方法,从可持续生物质中生产增值活性炭,可能用于高性能储能。
Trichosanthes Cucumerina Derived Activated Carbon: The Potential Electrode material for High Energy Symmetric Supercapacitor
High surface area porous activated carbons obtained from sustainable biomass are excellent functional materials for energy storage applications. This is the first report on snake gourd (Trichosanthes cucumerina) pericarp as a raw material of activated carbon and supercapacitor electrode material. Herein, a simple KOH activation and carbonisation method is used. The obtained SGC900 sample has a surface area of 1841 m2/g and an average pore volume of 0.52 cm3/g. SGC900 based supercapacitor exhibits good electrochemical storage capacity in 1 M H2SO4 with a specific capacitance of 206 F/g at 1 A/g. The symmetric device delivered an energy density of 11 Wh/kg at a power density of 1.6 kW/kg. It provides a series resistance (Rs) of 1.2 Ω and a charge transfer resistance Rct of 1.9 Ω. Furthermore, the device retains 95 % of capacitance over 5000 cycles. This work presents an easy and feasible approach for producing value-added activated carbon from sustainable biomass, potentially used in high-performance energy storage.
ChemNanoMatEnergy-Energy Engineering and Power Technology
CiteScore
6.10
自引率
2.60%
发文量
236
期刊介绍:
ChemNanoMat is a new journal published in close cooperation with the teams of Angewandte Chemie and Advanced Materials, and is the new sister journal to Chemistry—An Asian Journal.