{"title":"二硫化碳与丙二腈三聚物反应合成功能取代的 4H-Thiopyrans","authors":"K. V. Lipin, S. A. Blinov, I. N. Bardasov","doi":"10.1134/S1070428024100038","DOIUrl":null,"url":null,"abstract":"<p>Tripotassium 2-(1-cyano-2,2-disulfidoethenyl)-1,1,3,3-tetracyanopropenide was synthesized for the first time by the reaction of carbon disulfide and malononitrile trimer. Its further transformations afforded 2-amino-4-(dicyanomethylidene)-4<i>H</i>-thiopyran-3,5-dicarbonitrile derivatives.</p>","PeriodicalId":766,"journal":{"name":"Russian Journal of Organic Chemistry","volume":"60 10","pages":"1897 - 1900"},"PeriodicalIF":0.8000,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1070428024100038.pdf","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Functionally Substituted 4H-Thiopyrans by Reaction of Carbon Disulfide with Malononitrile Trimer\",\"authors\":\"K. V. Lipin, S. A. Blinov, I. N. Bardasov\",\"doi\":\"10.1134/S1070428024100038\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Tripotassium 2-(1-cyano-2,2-disulfidoethenyl)-1,1,3,3-tetracyanopropenide was synthesized for the first time by the reaction of carbon disulfide and malononitrile trimer. Its further transformations afforded 2-amino-4-(dicyanomethylidene)-4<i>H</i>-thiopyran-3,5-dicarbonitrile derivatives.</p>\",\"PeriodicalId\":766,\"journal\":{\"name\":\"Russian Journal of Organic Chemistry\",\"volume\":\"60 10\",\"pages\":\"1897 - 1900\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-12-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1134/S1070428024100038.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Organic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070428024100038\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070428024100038","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Synthesis of Functionally Substituted 4H-Thiopyrans by Reaction of Carbon Disulfide with Malononitrile Trimer
Tripotassium 2-(1-cyano-2,2-disulfidoethenyl)-1,1,3,3-tetracyanopropenide was synthesized for the first time by the reaction of carbon disulfide and malononitrile trimer. Its further transformations afforded 2-amino-4-(dicyanomethylidene)-4H-thiopyran-3,5-dicarbonitrile derivatives.
期刊介绍:
Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.