通过 Fenton 工艺转化牛皮纸木质素的动力学分析:工艺优化和随机建模†。

IF 3.4 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Lucas Ramos, Giovani Maltempi-Mendes, Adriano Francisco Siqueira, Diovana Aparecida dos Santos Napoleão and Anuj Kumar Chandel
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引用次数: 0

摘要

本文章由计算机程序翻译,如有差异,请以英文原文为准。

Kinetic analysis of kraft lignin conversion via the Fenton process: process optimization and stochastic modelling†

Kinetic analysis of kraft lignin conversion via the Fenton process: process optimization and stochastic modelling†

Lignin is a macromolecule with a highly branched and complex structure, making it difficult to degrade. It is a by-product of the pulp and paper industry and extensive treatment is required to mitigate environmental issues associated with effluent discharge. As an alternative, lignin can be treated through advanced oxidative processes (AOPs) using the Fenton reaction, which involves hydrogen peroxide (H2O2) and iron ions. In this context, a rotational central composite design (RCCD) was conducted to optimize lignin degradation using different molar ratios of H2O2/Fe2+ and H2O2/Fe3+ to assess the synergistic catalytic action of ions. The reactions were conducted in a batch reactor (2 L capacity), and a kinetic study of lignin degradation was performed using a stochastic model to characterize the oxidative process. Optimized conditions for the Fenton reaction were predicted, adopting a molar ratio of H2O2/Fe2+ of 9.0 and H2O2/Fe3+ of 6.0. The optimal conditions resulted in a 47.3% reduction in total organic carbon (TOC), reaching a conversion of over 80% in the depolymerization process. A quadratic model performed for the response variable TOC reduction showed a correlation coefficient (R2) of 0.926, indicating the model's quality and its ability to predict the variable with the greatest influence on the lignin depolymerization process. Further, Pseudomonas putida exhibited growth on low-molecular-weight aromatic molecules after depolymerization of kraft lignin.

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来源期刊
Reaction Chemistry & Engineering
Reaction Chemistry & Engineering Chemistry-Chemistry (miscellaneous)
CiteScore
6.60
自引率
7.70%
发文量
227
期刊介绍: Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society. From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.
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