{"title":"用于二氧化碳捕获和转化耦合过程的双功能催化剂:小视角","authors":"Chengxiong Dang and Hao Yu","doi":"10.1039/D4RE00334A","DOIUrl":null,"url":null,"abstract":"<p >The integrated CO<small><sub>2</sub></small> capture and utilization (ICCU) process can simultaneously achieve the reduction of CO<small><sub>2</sub></small> emissions and the production of high-value products. Bifunctional catalysts with coupled catalytic and adsorption functions show great potential in the realization of ICCU. The aim of this study is to comprehensively review the recent research progress in the development of bifunctional catalysts. We first review the bifunctional catalysts used in the integrated CO<small><sub>2</sub></small> capture and hydrogenation reaction including the RWGS and methanation reaction (ICCU-RWGS and ICCU-methanation). The effects of the adsorbent and catalyst components of bifunctional catalysts on the performance of ICCU-RWGS and ICCU-methanation including adsorption efficiency and catalytic activity are summarized. Then, we present the bifunctional catalysts applied in the integrated CO<small><sub>2</sub></small> capture and dry reforming reaction (ICCU-DR). The optimization of bifunctional catalysts to improve their cyclic stability is reviewed. Finally, the applications of bifunctional catalysts that were developed for the integrated ICCU and sorption-enhanced steam reforming (SESR) reaction are demonstrated.</p>","PeriodicalId":101,"journal":{"name":"Reaction Chemistry & Engineering","volume":" 1","pages":" 10-21"},"PeriodicalIF":3.4000,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bifunctional catalysts for the coupling processes of CO2 capture and conversion: a minireview\",\"authors\":\"Chengxiong Dang and Hao Yu\",\"doi\":\"10.1039/D4RE00334A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The integrated CO<small><sub>2</sub></small> capture and utilization (ICCU) process can simultaneously achieve the reduction of CO<small><sub>2</sub></small> emissions and the production of high-value products. Bifunctional catalysts with coupled catalytic and adsorption functions show great potential in the realization of ICCU. The aim of this study is to comprehensively review the recent research progress in the development of bifunctional catalysts. We first review the bifunctional catalysts used in the integrated CO<small><sub>2</sub></small> capture and hydrogenation reaction including the RWGS and methanation reaction (ICCU-RWGS and ICCU-methanation). The effects of the adsorbent and catalyst components of bifunctional catalysts on the performance of ICCU-RWGS and ICCU-methanation including adsorption efficiency and catalytic activity are summarized. Then, we present the bifunctional catalysts applied in the integrated CO<small><sub>2</sub></small> capture and dry reforming reaction (ICCU-DR). The optimization of bifunctional catalysts to improve their cyclic stability is reviewed. Finally, the applications of bifunctional catalysts that were developed for the integrated ICCU and sorption-enhanced steam reforming (SESR) reaction are demonstrated.</p>\",\"PeriodicalId\":101,\"journal\":{\"name\":\"Reaction Chemistry & Engineering\",\"volume\":\" 1\",\"pages\":\" 10-21\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2024-10-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reaction Chemistry & Engineering\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/re/d4re00334a\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reaction Chemistry & Engineering","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/re/d4re00334a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Bifunctional catalysts for the coupling processes of CO2 capture and conversion: a minireview
The integrated CO2 capture and utilization (ICCU) process can simultaneously achieve the reduction of CO2 emissions and the production of high-value products. Bifunctional catalysts with coupled catalytic and adsorption functions show great potential in the realization of ICCU. The aim of this study is to comprehensively review the recent research progress in the development of bifunctional catalysts. We first review the bifunctional catalysts used in the integrated CO2 capture and hydrogenation reaction including the RWGS and methanation reaction (ICCU-RWGS and ICCU-methanation). The effects of the adsorbent and catalyst components of bifunctional catalysts on the performance of ICCU-RWGS and ICCU-methanation including adsorption efficiency and catalytic activity are summarized. Then, we present the bifunctional catalysts applied in the integrated CO2 capture and dry reforming reaction (ICCU-DR). The optimization of bifunctional catalysts to improve their cyclic stability is reviewed. Finally, the applications of bifunctional catalysts that were developed for the integrated ICCU and sorption-enhanced steam reforming (SESR) reaction are demonstrated.
期刊介绍:
Reaction Chemistry & Engineering is a new journal reporting cutting edge research into all aspects of making molecules for the benefit of fundamental research, applied processes and wider society.
From fundamental, molecular-level chemistry to large scale chemical production, Reaction Chemistry & Engineering brings together communities of chemists and chemical engineers working to ensure the crucial role of reaction chemistry in today’s world.