利用碳纤维间距复合电极驾驭独立式柔性双碳锂离子电容器

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
Subhajit Bhowmik, Satyabati Mishra, Maurya Akshaykumar R, Udita Bhattacharjee and Surendra K. Martha*, 
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引用次数: 0

摘要

双碳锂离子电容器(dc - lic)已成为解决高能量密度锂离子电池(LIBs)和高功率密度超级电容器(SCs)之间差距的一种有希望的解决方案。然而,两个电极之间的动力学差异限制了它们的应用。本课题主要研究了利用储量丰富的石油沥青前驱体和碳纤维垫集流材料合成碳基负极材料并对其进行优化。阳极是通过沥青和硫脲的水热煅烧,然后使用额外的沥青(不含粘合剂和额外的炭黑)包裹一层水热衍生碳来开发的。同时,阴极是通过KOH活化得到的活性炭。在本研究中,利用在CF (CFP8)表面涂覆N, s掺杂碳作为阳极可以解决活性炭阴极(ACP8)的高速率性能。此外,使用CF作为电流收集器使这种LIC器件更加灵活和可持续。因此,优化后的dc - lic(1.5:1质量比)在8300 W kg-1的高功率密度下具有63 Wh kg-1的优越能量密度。此外,这种基于cf的柔性DC-LIC器件即使在10 000次循环后也能保持75%的容量。因此,这一发现强调了dc - lic的潜力,突出了与传统超级电容器相比改进的能量,自放电和泄漏电流。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Harnessing Free-Standing Flexible Dual Carbon Lithium-Ion Capacitors with Carbon Fiber–Pitch Composite Electrodes

Harnessing Free-Standing Flexible Dual Carbon Lithium-Ion Capacitors with Carbon Fiber–Pitch Composite Electrodes

Dual carbon lithium-ion capacitors (DC-LICs) have emerged as a promising solution to reconcile the disparity between high-energy-density lithium-ion batteries (LIBs) and high-power-density supercapacitors (SCs). However, the kinetic discrepancy between the two electrodes limits their applications. This research focuses on synthesizing and optimizing carbon-based anode and cathode materials from a widely abundant petroleum pitch precursor and carbon fiber (CF) mat current collector. The anode is developed through hydrothermal-calcination of pitch and thiourea, followed by a coating of hydrothermal-derived carbon using additional pitch (without binder and additional carbon black). At the same time, the cathode is activated carbon obtained by KOH activation. Herein, the utilization of N, S-doped carbon coated on CF (CFP8) as an anode can tackle the high rate performance of the activated carbon cathode (ACP8). Further, using CF as a current collector makes this LIC device flexible and more sustainable. Thus, the optimized DC-LICs (1.5:1 mass ratio) exhibit a superior energy density of 63 Wh kg–1 at a high power density of 8300 W kg–1. Besides, this CF-based flexible DC-LIC device exhibits 75% retention in capacity even after 10 000 cycles. Thus, this finding emphasizes the potential of DC-LICs, highlighting the improved energy, self-discharge, and leakage current compared with traditional supercapacitors.

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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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