Zhengrong Liu, Zilin Zhou, Jiaming Yang, Yueyue Sun, Chaofan Yin, Ruhuan Li, Kai Wu, Athanasios Chatzitakis and Jun Zhou*,
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引用次数: 0
摘要
固体氧化物电解电池(SOECs)中的传统氧电极(La,Sr)(Co,Fe)O3 (LSCF)存在成本高、高温蒸发和Co使用的社会问题。在本工作中,合成了一种无Co的b位多元素(所谓的高熵)钙钛矿氧化物La0.6Sr0.4Cu0.2Fe0.2Ti0.2Mn0.2Ni0.2O3-δ (LSCuFTMN),并成功地作为一种新型氧电极应用。x射线光电子能谱(XPS)数据表明,b位的多个过渡元素以不同的价态存在,导致电子结构在空间上变化。LSCuFTMN的电化学测量表明,该材料在研究的工作气氛下表现出非凡的催化活性和稳定性,极化电阻比LSCF降低了24%。通过弛豫时间(DRT)分布分析,LSCuFTMN具有比传统LSCF更好的质量和电荷传递性能。以LSCuFTMN为氧电极的SOEC进行了组装和测试,在2.0 V和800°C电解纯CO2时获得了1.2 a cm-2的电流密度,比LSCF高近50%。法拉第效率在95%以上。在长期稳定性测试中没有观察到明显的衰退。显然,多离子化——所谓的高熵氧化物——可能是改善soec工作性能的有前途的材料。
Design of a B-Site Co-Free Multielement Perovskite Oxide as Oxygen Electrode for Efficient CO2 Solid Oxide Electrolysis Cells
The traditional oxygen electrode in solid oxide electrolysis cells (SOECs), (La,Sr)(Co,Fe)O3 (LSCF), suffers from high cost, evaporation at high temperatures, and societal aspects of the use of Co. In this work, a Co-free B-site multielement (so-called high-entropy) perovskite oxide, La0.6Sr0.4Cu0.2Fe0.2Ti0.2Mn0.2Ni0.2O3-δ (LSCuFTMN), has been synthesized and successfully applied as a novel oxygen electrode. X-ray photoelectron spectroscopy (XPS) data indicate that the multiple transition elements in the B-site exist in various valence states, leading to a spatially variable electron structure. Electrochemical measurements of LSCuFTMN suggest that the material exhibits extraordinary catalytic activity and stability under the studied working atmospheres and a decrease in polarization resistance by 24% compared to LSCF. By distribution of relaxation time (DRT) analysis, LSCuFTMN possesses better mass and charge transfer performance than traditional LSCF. An SOEC with LSCuFTMN as the oxygen electrode has been assembled and tested, and a current density of 1.2 A cm–2 is obtained at 2.0 V and 800 °C in electrolysis of pure CO2, higher by nearly 50% compared to LSCF. The faradaic efficiency is over 95%. No clear recession is observed in the long term stability test. It is evident that multication – so-called high-entropy – oxides could be promising materials for improving the working performance of SOECs.
期刊介绍:
ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.