通过构建金属有机框架和掺杂镧系元素的纳米粒子复合材料动态控制上转换发光†。

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
CrystEngComm Pub Date : 2024-11-21 DOI:10.1039/D4CE00932K
Huiwen Yan, Wenqian Cao, Zhiyu Wang, Yuanjing Cui and Guodong Qian
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引用次数: 0

摘要

多光子上转换的动态操控可实现丰富而可调的发射颜色,这引起了人们对掺镧上转换纳米粒子(UCNPs)基础研究和前沿应用的极大兴趣。然而,如何在不进行繁琐的内源调节的情况下操纵单个 UCNP 发射体的光致变色上转换发射,实现发光颜色调谐(LCT),仍然是一项具有挑战性的工作。在本研究中,通过一种简单而多用途的原位合成方法,将 NaYF4@NaYF4:x%Yb, 2%Er (X = 60, 80 and 98) 与 UiO-66 型金属有机框架(MOFs,包括 UiO-66、UiO-66-NDC、UiO-66-NH2)结合在一起。UCNPs 与 MOFs 以单分散状态结合在一起,与单独的 UCNPs 相比,复合材料的稳定性得到了提高。通过利用 MOFs 中具有高能振动的化学键,促进了 Er3+ 的多声子弛豫(MPR)过程,实现了对 UCNPs 上转换发光(UCL)特性的有效调制。我们的研究成果实现了对发光材料发射颜色的多功能设计和动态控制,为其先进的光子应用开辟了新的机遇,特别是在光学防伪领域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Dynamic manipulation of upconversion luminescence by constructing metal–organic framework and lanthanide-doped nanoparticle composites†

Dynamic manipulation of upconversion luminescence by constructing metal–organic framework and lanthanide-doped nanoparticle composites†

The dynamic manipulation of multi-photon upconversion, enabling rich and tunable emission colors, has generated significant interest in lanthanide-doped upconversion nanoparticles (UCNPs) about their fundamental research and frontier applications. However, manipulating photochromic upconversion emissions towards luminescent color tuning (LCT) of a single UCNP emitter without tedious endogenous regulation remains a challenging endeavor. In this study, NaYF4@NaYF4:x%Yb, 2%Er (X = 60, 80 and 98) was incorporated with UiO-66-type metal–organic frameworks (MOFs, including UiO-66, UiO-66-NDC, UiO-66-NH2) by a simple and versatile in situ synthesis method. The UCNPs are combined with MOFs in a monodisperse state, and the stability of the composites is improved compared to UCNPs alone. Effective modulation of the upconversion luminescence (UCL) properties of UCNPs was achieved by exploiting the chemical bonds with high-energy vibrations in MOFs, which facilitates the multi-phonon relaxation (MPR) processes of Er3+. Our findings enable versatile designs and dynamic control of emission colors from luminescent materials, opening up new opportunities for their advanced photonic applications, notably in optical anti-counterfeiting.

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来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍: Design and understanding of solid-state and crystalline materials
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