制浆材料中的木质素对锌离子混合电容器黑液衍生碳阴极储能性能的结构影响。

IF 9.4 1区 化学 Q1 CHEMISTRY, PHYSICAL
Yanjie Yi , Songqing Hu , Yuyang Ma , Tao Tang , Chao Liu , Ying Yan , Lirong Lei , Yi Hou
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引用次数: 0

摘要

蒸煮黑液在制浆过程中产生,是一种很有前途的电极材料,可直接作为碳源应用。本文研究了木质素的微观结构与从各种植物(包括软木、硬木和草)中提取的黑液中提取的碳的电化学性质之间的关系。结果表明,桉树黑液中含有丰富的甲氧基,对炭素材料性能的影响显著高于松黑液和竹黑液。丰富的甲氧基有助于微孔的形成,并促进木质素侧链上的氧原子进入碳基体。这一过程产生了多孔碳结构,具有可观的比表面积(1599 m2/g)和5.4%的氧含量,有利于电荷转移和降低吸附能势(从-0.17 eV降至-0.36 eV)。制备的单电极比电容达到271 gf -1。此外,利用桉树黑液生产的碳阴极的锌离子混合电容器实现了71.8 Wh kg-1的最大能量密度和1.11 kW kg-1的功率密度。本研究为优化高能量存储装置电极材料的工业生产提供了原料选择建议。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The structure impact of lignin in pulping material on the energy storage performance of black liquor derived carbon cathodes for zinc ion hybrid capacitors

The structure impact of lignin in pulping material on the energy storage performance of black liquor derived carbon cathodes for zinc ion hybrid capacitors
Cooking black liquors generated during the pulping process have been recognized as promising electrode materials which can be directly applied as carbon sources. This paper investigates the relationship between the microstructure of lignin and the electrochemical properties of carbon derived from black liquor obtained from various plants, including softwood, hardwood, and grass. It was found that eucalyptus black liquor, abundant in methoxy groups, has a notable impact on the performance of carbon materials compared to black liquor derived from Pinus sylvestris and bamboo. The abundant methoxy groups contribute to micropore formation and facilitate the incorporation of oxygen atoms from the lignin side chains into the carbon matrix. This process results in a porous carbon structure with a substantial specific surface area (1599 m2/g) and an oxygen content of 5.4 %, which facilitate charge transfer and reduce the adsorption energy barrier (from −0.17 eV to −0.36 eV). The specific capacitance of the prepared single electrode reaches 271 F g−1. Additionally, a zinc ion hybrid capacitor utilizing a carbon cathode produced from eucalyptus black liquor achieves a maximum energy density of 71.8 Wh kg−1 and a power density of 1.11 kW kg−1. This work offers recommendations for selecting raw materials to optimize the industrial production of electrode materials for high energy storage devices.
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来源期刊
CiteScore
16.10
自引率
7.10%
发文量
2568
审稿时长
2 months
期刊介绍: The Journal of Colloid and Interface Science publishes original research findings on the fundamental principles of colloid and interface science, as well as innovative applications in various fields. The criteria for publication include impact, quality, novelty, and originality. Emphasis: The journal emphasizes fundamental scientific innovation within the following categories: A.Colloidal Materials and Nanomaterials B.Soft Colloidal and Self-Assembly Systems C.Adsorption, Catalysis, and Electrochemistry D.Interfacial Processes, Capillarity, and Wetting E.Biomaterials and Nanomedicine F.Energy Conversion and Storage, and Environmental Technologies
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