环氧苯乙烯-对苯二酚-氯化铜三元体系在甲醇溶液中的氧化反应

IF 1.4 4区化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL

Russian Journal of Physical Chemistry B Pub Date : 2024-12-11 DOI:10.1134/S199079312470091X

L. V. Petrov, V. M. Solyanikov

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引用次数: 0

摘要

研究了三元体系（TrS）（SE - HQ - cu (II)）在甲醇溶液中氧气氛下环氧苯乙烯（SE）和对苯二酚（HQ）的消耗。用压力计研究了SE-HQ-CuCl2 Trs的吸氧性能。在308 ~ 323 k的温度范围内，反应速度用试剂浓度表示为V = k[Cu(II)]1[HQ]0[SE]0，有效氧化速率常数k = 1.82 × 105exp(-40 kJ mol-1 /RT) s-1。讨论了TrS的氧化机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Oxidation of the Styrene Epoxide–Hydroquinone–Copper(II) Chloride Ternary System in a Methanol Solution

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Oxidation of the Styrene Epoxide–Hydroquinone–Copper(II) Chloride Ternary System in a Methanol Solution

The consumption of styrene epoxide (SE) and hydroquinone (HQ) in a ternary system (TrS) (SE–HQ–Cu(II)) in an oxygen atmosphere in a methanol solution is studied. The oxygen uptake by the SE–HQ–CuCl₂ Trs is studied manometrically. The expression of velocity in terms of the reagent concentrations V = k[Cu(II)]¹[HQ]⁰[SE]⁰ and the effective oxidation rate constant k = 1.82 × 10⁵exp(–40 kJ mol^–1/RT) s^–1 is obtained in the temperature range 308–323 K. The oxidation mechanism of the TrS is discussed.

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来源期刊

Russian Journal of Physical Chemistry B 化学-物理：原子、分子和化学物理

CiteScore

2.20

自引率

71.40%

发文量

106

审稿时长

4-8 weeks

期刊介绍： Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.