金属羟基酸盐的液晶行为

IF 1.4 4区化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL

Russian Journal of Physical Chemistry B Pub Date : 2024-12-11 DOI:10.1134/S1990793124700726

S. Shukla, N. Pandya, C. Sharma, M. Kureshi, Y. Agrawal

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引用次数: 0

摘要

为了更好地了解最近合成的金属羟基酸盐的液晶行为，光学显微镜和差示扫描量热法已经被使用。用热重法和差热分析法对其热稳定性和质量损失进行了分析。除n- 4-异丙氧基苯基-4′-正丁氧基肉桂羟肟酸配合物和铁羟肟酸配合物外，几乎所有金属羟肟酸都存在向列相中间相。n- 4-正丁氧基苯基-4′-正丁氧基肉桂羟肟酸和n- 4-异淀粉基苯基-4′-正丁氧基肉桂羟肟酸的铜（II）羟酸配合物表现出向列性和近晶性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Liquid Crystalline Behavior of Metal–Hydroxamates

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Liquid Crystalline Behavior of Metal–Hydroxamates

In order to better understand the liquid crystalline behavior of recently synthesized metal hydroxamates, optical microscopy and differential scanning calorimetry have been employed. Analysis of their thermal stability and loss of mass by thermogravimetry and differential thermal analysis has been performed. The nematic mesophase can be observed in nearly all metal hydroxamates, with the exception of N-4-isopropoxyphenyl-4'-n-butoxycinnamohydroxamic acid complexes and iron hydroxamic acid complexes. Copper(II) hydroxamate complexes of N-4-n-butoxyphenyl-4'-n-butoxycinnamo hydroxamic acid and N-4-isoamyloxyphenyl-4'-n-butoxycinnamohydroxamic acid exhibit nematic as well as smectic behavior.

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来源期刊

Russian Journal of Physical Chemistry B 化学-物理：原子、分子和化学物理

CiteScore

2.20

自引率

71.40%

发文量

106

审稿时长

4-8 weeks

期刊介绍： Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.