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n -氯喹啉与氯的配合物：通过氯原子形成的强卤素键合

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
CrystEngComm Pub Date : 2024-11-19 DOI:10.1039/D4CE01053A
Maison Hardin, Matthias Zeller and Sergiy V. Rosokha
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引用次数: 0

摘要

n -氯糖与喹啉（QN）结晶产生的QN- cl +阳离子显示氯和叔氮原子之间的共价键。在它们的2:1和1:1配合物中，QN-Cl+和Cl−阴离子之间的强（超分子）卤素键构成了轨道（共价）相互作用的很大一部分。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

Complexes of N-chloroquinuclidinium with chloride: strong halogen bonding via chlorine atoms†

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Complexes of N-chloroquinuclidinium with chloride: strong halogen bonding via chlorine atoms†

Crystallization of N-chlorosaccharin with quinuclidine (QN) produced QN-Cl+ cations showing a covalent bond between chlorine and a tertiary nitrogen atom. Strong (supramolecular) halogen bonds between the QN-Cl+ and Cl− anions in their 2 : 1 and 1 : 1 complexes comprise a large contribution of orbital (covalent) interactions.

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来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍： Design and understanding of solid-state and crystalline materials
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