通过介孔氧化铟组成的双金属氧化还原对同时去除 NO 和 CO

IF 3.2 3区 化学 Q2 CHEMISTRY, PHYSICAL
Rahul D. Kerkar, Arun V. Salker
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引用次数: 0

摘要

设计具有双或三金属芯的新型催化材料以获得更高的催化性能是当前研究的一个关键方面。本研究描述了通过甘氨酸燃烧途径合成的铟基复合催化剂将有毒CO和NO转化为无毒CO和NO的效果。在所制备的材料中,钴-铜复合氧化铟催化剂对CO和NO的解毒性能最好。介孔催化剂的氧化还原性能得到显著改善,CO-O2在160℃下转化,NO-CO在220℃下转化。通过TPR曲线可以证明,Co和Cu的插入倾向于增强氧化还原对,这是由于Co2+/3+ -Cu1 +/2+之间的协同相互作用。所提出的铟、铜和钴的三金属核心促进了高表面性能,突出了在NO和CO转化催化剂设计中精确有效性的重要性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Simultaneous NO and CO Removal through Bimetallic Redox Pairs Composed of Mesoporous Indium Oxide

Simultaneous NO and CO Removal through Bimetallic Redox Pairs Composed of Mesoporous Indium Oxide
Designing new catalytic materials with bi- or trimetallic cores for higher catalytic performance is a key aspect of current research. The current research describes the effect of an indium-based composite catalyst, synthesized through the glycine combustion route, for the conversion of toxic CO and NO into nontoxic ones. Among the prepared materials, the cobalt–copper-composed indium oxide catalyst exhibited the highest performance in detoxifying CO and NO. The notable improvement in the redox nature of the mesoporous catalyst displayed the CO–O2 conversion at 160 °C and NO–CO conversion at 220 °C, respectively. The insertion of Co along with Cu tends to enhance the redox pair as attributed to the synergistic interplay among Co2+/3+–Cu1+/2+, as evidenced through the TPR profile. The presented trimetallic core of indium, copper, and cobalt facilitates high surface properties, highlighting the importance of precise effectiveness in catalyst design in NO and CO conversion.
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来源期刊
The Journal of Physical Chemistry C
The Journal of Physical Chemistry C 化学-材料科学:综合
CiteScore
6.50
自引率
8.10%
发文量
2047
审稿时长
1.8 months
期刊介绍: The Journal of Physical Chemistry A/B/C is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, and chemical physicists.
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