{"title":"2,4-Di-chloro-6-{<i>N</i>-[2-(tri-fluoro-meth-yl)phen-yl]carboximido-yl}phenol.","authors":"Zizipho Xantini, Alfred Muller, Koop Lammertsma","doi":"10.1107/S2414314624010745","DOIUrl":null,"url":null,"abstract":"<p><p>The title compound, C<sub>14</sub>H<sub>8</sub>Cl<sub>2</sub>F<sub>3</sub>NO, was synthesized by the condensation between tri-fluoro-methyl-aniline and di-chloro-salicyl-aldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an ortho-rhom-bic <i>Pbca</i> (<i>Z</i> = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the mol-ecules pack together to form a zigzag pattern along the <i>c</i> axis.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 Pt 11","pages":"x241074"},"PeriodicalIF":0.0000,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618864/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314624010745","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
标题化合物 C14H8Cl2F3NO 是由三氟甲基苯胺和二氯水杨醛通过亲核加成缩合而成，形成半氨基，然后脱水生成亚胺。该化合物结晶于正交双室 Pbca（Z = 8）空间群，两个芳香环之间的二面角为 44.70 (5)°。在晶体中，分子胚珠沿着 c 轴聚集在一起，形成人字形图案。
The title compound, C14H8Cl2F3NO, was synthesized by the condensation between tri-fluoro-methyl-aniline and di-chloro-salicyl-aldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an ortho-rhom-bic Pbca (Z = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the mol-ecules pack together to form a zigzag pattern along the c axis.
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