碱性促进[60]富勒烯与h -膦酸盐和烷基溴的1,4-二官能化

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2024-12-05 DOI:10.1021/acs.orglett.4c03977

Yi Wang, Ruo-Yu Jiang, Si-Jie Huang, Jun Xuan, Hong-Ping Zhou, Fei Li

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引用次数: 0

摘要

dbu促进h -膦酸盐、[60]富勒烯和烷基溴的三组分偶联反应是一种简便、高效的一锅合成各种1,4-（膦基）（有机）[60]富勒烯的方法。该方法在[60]富勒烯核心的1,4位置具有高的区域选择性，并且具有无金属性质，操作简单，成本低，底物范围广的特点。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Base-Promoted 1,4-Difunctionalization of [60]Fullerene with H-Phosphonates and Alkyl Bromides

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Base-Promoted 1,4-Difunctionalization of [60]Fullerene with H-Phosphonates and Alkyl Bromides

The DBU-promoted three-component coupling reaction of H-phosphonates, [60]fullerene, and alkyl bromides has been developed as a facile and efficient protocol for the one-pot synthesis of various 1,4-(phosphonyl)(organo)[60]fullerenes. This method exhibits high regioselectivity at the 1,4-position on the [60]fullerene core and features a metal-free nature, easy operation, low cost, and a wide range of substrates.

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.